A2 Organic Chemistry Reactions, Reagents and Conditions Flashcards

5724798878	Change of Functional Group in "Oxidation of Aldehydes".	Aldehyde to Carboxylic Acid	0
5724812033	Reagent in "Oxidation of Aldehydes"	Potassium dichromate (VI) solution and dilute sulphuric acid	1
5724815289	Conditions of "Oxidation of Aldehydes"	Heat under Reflux	2
5724822838	Forming Tollen's Reagent	Aqueous Ammonia and Silver Nitrate.	3
5724829089	Complex Ion in Tollen's Reagent	[Ag(NH3)2]+	4
5724839039	Conditions for Tollen's Reagent	Heat Gently.	5
5724845727	Tollen's Reagent vs Aldehyde Chemical Changes	Oxidised into a carboxylic acid and silver (I) ions are reduced to silver atoms.	6
5724857179	Tollen's Reagent vs Aldehyde Observation.	SIlver Mirror forms.	7
5724859624	Tollen's Reagent vs Ketone	No change.	8
5724868124	Fehling's Solution Conditions	Heat Gently	9
5724874952	Fehling's Solution vs Aldehyde Chemical Changes	Oxidised into a carboxylic acid and copper ions are reduced to copper (I) oxide.	10
5724882485	Fehling's Solution vs Aldehyde Observation.	Blue Cu2+ ions in solution change to red precipitate of Cu2O.	11
5724904605	Fehling's Solution vs Ketone	No reaction.	12
5724907150	Reduction of Carbonyls Reagents	NaBH4 in aqueous ethanol	13
5724917093	Reduction of Carbonyls Condition	Room temperature and pressure.	14
5724929060	What does Catalytic Hydrogenation do?	Reduce Carbonyls.	15
5724932324	Catalytic Hydrogenation Reagent	Hydrogen and nickel catalsyt.	16
5724953078	Catalytic Hydrogenation Condition	High Pressure	17
5734537917	Carbonyl to Hydroxynitriles Reagent	Sodium Cyanide (NaCN) and dilute Sulphuric Acid	18
5734552542	Carbonyl to Hydroxynitriles Conditions	Room temperature and pressure	19
5734563694	Carbonyl to Hydroxynitriles Mechanism	Nucleophilic Addition	20
5734624827	Hydrolysis of Ester using Acid Reagents	Dilute Acid HCl	21
5734630164	Hydrolysis of Ester using Acid Conditions	Heat under Reflux	22
5734631554	Hydrolysis of Ester using Alkali Reagents	Dilute Sodium Hydroxide	23
5734647247	Hydrolyiss of Ester using Alkali Conditions	Heat under Reflux	24
5734658518	Acyl Chlorides Reaction with Water Change in Functional Group	Acyl Chloride -> Carboxylic Acid	25
5734671303	Acyl Chlorides Reaction with Water Reagent	Water	26
5734671304	Acyl Chlorides Reaction with Water Conditions	Room Temperature	27
5734686286	Acid Anhydrides Reaction with Water Change in Functional Group	Acid Anhydride -> Carboxylic Acid	28
5734688840	Acid Anhydrides Reaction with Water Reagent	Water	29
5734690937	Acid Anhydrides Reaction with Water Conditions	Room temp.	30
5734697935	Acyl Chlorides Reaction with Alcohol Change in Fuctional Group	Acyl Chloride -> Water	31
5734700734	Acyl Chlorides Reaction with Alcohol Reagent	Alcohol	32
5734700735	Acyl Chlorides Reaction with Alcohol Conditions	Room Temperature	33
5734707198	Acid Anhydride Reaction with Alcohol Change in Fuctional Group	Acid Anhydride -> Ester	34
5734712047	Acid Anhydride Reaction with Alcohol Reagent	Alcohol	35
5734712050	Acid Anhydride Reaction with Alcohol Conditions	Room Temperature	36
5734735744	Acyl Chlorides Reaction with Ammonia Change in Functional Group	Acyl Chloride -> Primary Amide	37
5734743262	Acyl Chlorides Reaction with Ammonia Reagent	Ammonia	38
5734743346	Acyl Chlorides Reaction with Ammonia Conditions	Room Temperature	39
5734781588	Acid Anhydride Reaction with Ammonia Change in Fuctional Group	Acid Anhydride -> Primary Amide	40
5734783660	Acid Anhydride Reaction with Ammonia Reagent	Ammonia	41
5734791056	Acid Anhydride Reaction with Ammonia Conditions	Room Temperature	42
5734796570	Acyl Chlorides Reaction with Primary Amines Change in Functional Group	Acyl Chloride -> Secondary Amine	43
5734799988	Acyl Chlorides Reaction with Primary Amines Reagent	Primary Amine	44
5734799989	Acyl Chlorides Reaction with Primary Amines Conditions	Room Temperature	45
5734806875	Acid Anhydride Reaction with Primary Amines Change in Functional Group	Acid Anhydride -> Secondary Amide	46
5734808827	Acid Anhydride Reaction with Primary Amines Reagent	Primary Amine	47
5734808828	Acid Anhydride Reaction with Primary Amines Conditions	Room Temp.	48
5734823428	Nitration of Benzene Change in Fuctional Group	Benzene -> Nitrobenzene	49
5734826955	Nitration of Benzene Reagents	Conc. nitric acid in the presence of concentrated sulphuric acid (catalyst).	50
5734830110	Nitration of Benzene Mechanism	Electrophilic Substituion	51
5734832337	Nitration of Benzene Electrophile	NO2+	52
5734843359	Friedel Crafts Acylation Change in Functional Group	Benzene -> phenyl ketone	53
5734847388	Friedel Crafts Acylation Reagents	Acyl chloride in presence of anhydrous aluminium chloride catalyst	54
5734853889	Friedel Crafts Acylation Conditions	Heat under Reflux (50c)	55
5734863966	Friedel Crafts Acylation Mechanism	Electrophilic Substituion	56
5734869064	Reducing a Nitroarene to Aromatic Amines Reagent	Sn and HCl or Fe and HCl	57
5734872495	Reducing a Nitroarene to Aromatic Amines Conditions	Heating	58
5734872562	Reducing a Nitroarene to Aromatic Amines Mechanism	Reduction	59
5734889199	Preparing Amines from Nitriles: Step 1 and reagents/conditions	Convert Haloalkane to Nitrile using KCN in ethanol (heat under reflux)	60
5734894449	Preparing Amines from Nitriles: Step 2 and reagents/conditions	Reduce nitrile to amine by using LiAlH4 in ether or by reducing with H2 using a Ni catalyst.	61
5734948450	Acid + Metal	Salt + Hydrogen	62
5734950627	Acid + Alkali	Salt + Water	63
5734950630	Acid + Carbonate	Salt + Water + Carbon Dioxide.	64
5734962550	Nitration of Benzene Equation for Formation of Electrophile	HNO3 + 2H2SO4 -> (NO2+) +(2HSO4-) +(H3O+)	65
5734988052	Friedel Craft Acylation Equation for Formation of the electrophile	AlCl3 + Ch3COCl -> CH3CO+AlC4-	66