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Wave Behavior of Matter, Quantum Mechanics

matter waves - describes wave characteristics of material particles  

  • all matter have wavelengths
  • wavelength inversely proportional to mass/velocity
  • l = Planck's constant / (mass x velocity) = h / mv
  • microscopes use wave properties of electrons to map out surfaces

quantum (wave) mechanics - studies w/ subatomic particles  

  • wave functions - mathematical functions describing electron's matter wave
    • represented by y, but has no physical meaning by itself
    • probability density = y2
    • electron density - areas w/ high probability of finding electrons
  • orbital - describes distribution of electron density in space
    • not the same as the orbits mentioned in Bohr's model
    • path of electron can't be precisely tracked (due to uncertainty principle)
  • quantum numbers - n, l, ml used to describe orbitals
    • n = positive integer, principle quantum number; increases as electron gets farther away from nucleus
    • En = (-2.18 x 10-18 J)(1/n2)
    • l = integer from 0 to n-1, azimuthal quantum number; describes orbital shape
    • ml = integers between l and -l, magnetic quantum number; describes orientation of orbital
  • electron shell - collection of orbitals w/ same n value
  • subshell - orbitals w/ same n and l values
  • n subshells in the shell w/ principle quantum number n
  • each subshell has 2(l)+1 number of orbitals
  • n2 = total number of orbitals in a shell
  • ground state - electron in lowest energy orbital
  • excited state - electron in any other orbital, reaches this level by absorbing photons
Subject: 
Chemistry [1]
Subject X2: 
Chemistry [1]

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