CourseNotes
Published on CourseNotes (https://course-notes.org)

Home > AP Chemistry > Topic Notes > Periodic Properties of the Elements > Ionization Energy, Electron Affinities

Ionization Energy, Electron Affinities

ionization energy - measures amount of energy needed to lose an electron  

  • more difficult to remove electrons w/ greater ionization energy
  • more energy needed to remove each subsequent electron
  • sharp increase in ionization energy needed to remove inner shell electrons
    • inner shell electrons much closer to nucleus
  • I1 generally increases w/ atomic number on each row
  • I1 decreases as atomic number increases down a group
  • representative elements have larger range of I1 than transition elements
  • smaller atoms tend to have higher ionization energies (electrons closer to nucleus)

ion electron configurations - electrons removed from largest available quantum number first  

  • electrons added to lowest available quantum number first

electron affinity - energy change when electron is added to a gaseous atom  

  • measures attraction of atom for added electron
  • usually negative (energy usually released when electron is added), but can be positive for noble gases (anion higher in energy than separated atom/electron)
  • halogens have the most negative electron affinities
  • noble gases have positive electron affinities (when adding an electron would place it on a new energy subshell)
  • group 5A (w/ 1/2 filled subshells) have electron affinities either positive or less negative than group 4A
  • doesn't change much going up/down a group
Subject: 
Chemistry [1]
Subject X2: 
Chemistry [1]

Source URL:https://course-notes.org/chemistry/topic_notes/periodic_properties_of_the_elements/ionization_energy_electron_affinities#comment-0

Links
[1] https://course-notes.org/subject/chemistry