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Bases

definition - increases the concentration of OH- ions when dissolved in water  

  • Bronsted-Lowry definition - accepts proton from another substance
    • even applies to substances not dissolved in water
  • Lewis definition - electron-pair donor
  • pOH = -log [OH-]
    • pOH = 14 - pH
  • strong base - completely dissociates, [OH-] = [base]
    • hydroxides of alkali metals and heavy alkaline earth metals
  • weak base - partially dissociates
    • Kb = [OH-][conjugate acid] / [base]
    • [OH-] = [conjugate acid] when Kb is very small

Find the pH of 0.0030 M solution of ammonia  

  • Kb = 1.8 x 10-5
  • Kb = [OH-] [ammonium] / [ammonia] = x2 / 0.0030
  • x = [(1.8 x 10-5) (0.0030)]1/2 = 2.3 x 10-4 = [OH-]
  • pOH = -log [OH-] = 3.63
  • pH = 14 - 3.63 = 10.37
Subject: 
Chemistry [1]
Subject X2: 
Chemistry [1]

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