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Chemistry

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Chemistry The Central Science Chapter 9

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Chapter 9 Molecular Geometryand Bonding Theories James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation ? 2015 Pearson Education, Inc. 1 Molecular Shapes Lewis Structures show bonding and lone pairs, but do not denote shape. However, we use Lewis Structures to help us determine shapes. Here we see some common shapes for molecules with two or three atoms connected to a central atom. ? 2015 Pearson Education, Inc. Molecular Geometries and Bonding Theories 2 What Determines the Shape of a Molecule? Simply put, electron pairs, whether they be bonding or nonbonding, repel each other. By assuming the electron pairs are placed as far as possible from each other, we can predict the shape of the molecule. This is the Valence-Shell Electron-Pair Repulsion (VSEPR) model.

Chemistry The Central Science Chapter 8

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Chapter 8 Basic Concepts of Chemical Bonding James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation ? 2015 Pearson Education, Inc. 1 Chemical Bonds Three basic types of bonds Ionic Electrostatic attraction between ions. Covalent Sharing of electrons. Metallic Metal atoms bonded to several other atoms. Basic Concepts of Chemical Bonding ? 2015 Pearson Education, Inc. 2 Lewis Symbols G. N. Lewis developed a method to denote potential bonding electrons by using one dot for every valence electron around the element symbol. When forming compounds, atoms tend to gain, lose, or share electrons until they are surrounded by eight valence electrons (the octet rule). Basic Concepts of Chemical Bonding ? 2015 Pearson Education, Inc. Ionic Formation

Chemistry The Central Science Chapter 7

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James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation Chapter 7 Periodic Propertiesof the Elements ? 2015 Pearson Education, Inc. Development of the Periodic Table Dmitri Mendeleev and Lothar Meyer independently came to the same conclusion about how elements should be grouped. Periodic Properties of the Elements ? 2015 Pearson Education, Inc. 2 Mendeleev and the Periodic Table Chemists mostly credit Mendeleev because he also used chemical properties to organize the table and predicted some missing elements and their expected properties, including germanium. Periodic Properties of the Elements ? 2015 Pearson Education, Inc. 3 Atomic Number Mendeleev?s table was based on atomic masses. It was the most fundamental property of elements known at the time.

Chemistry The Central Science Chapter 6

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Lecture Presentation Chapter 6 Electronic Structure of Atoms James F. Kirby Quinnipiac University Hamden, CT Electronic Structure of Atoms ? 2015 Pearson Education, Inc. Electronic Structure This chapter is all about electronic structure?the arrangement and energy of electrons. It may seem odd to start by talking about waves. However, extremely small particles have properties that can only be explained in this manner! Electronic Structure of Atoms ? 2015 Pearson Education, Inc. Waves To understand the electronic structure of atoms, one must understand the nature of electromagnetic radiation. The distance between corresponding points on adjacent waves is the wavelength (?). Electronic Structure of Atoms ? 2015 Pearson Education, Inc. 3 Waves

Chemistry The Central Science Chapter 5

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Chapter 5 Thermochemistry James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation ? 2015 Pearson Education, Inc. 1 Energy Energy is the ability to do work or transfer heat. Energy used to cause an object that has mass to move is called work. Work = force x distance W = f x d Energy used to cause the temperature of an object to rise is called heat. This chapter is about thermodynamics, which is the study of energy transformations, and thermochemistry, which applies the field to chemical reactions, specifically. Thermochemistry ? 2015 Pearson Education, Inc. 2 Kinetic Energy Kinetic energy is energy an object possesses by virtue of its motion: Thermochemistry ? 2015 Pearson Education, Inc. 3 Potential Energy

Chemistry The Central Science Chapter 4

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Lecture Presentation Chapter 4 Reactions in Aqueous Solution James F. Kirby Quinnipiac University Hamden, CT Aqueous Reactions ? 2015 Pearson Education, Inc. Solutions Solutions are defined as homogeneous mixtures of two or more pure substances. The solvent is present in greatest abundance. All other substances are solutes. When water is the solvent, the solution is called an aqueous solution. Aqueous Reactions ? 2015 Pearson Education, Inc. 2 Aqueous Solutions Substances can dissolve in water by different ways: Ionic Compounds dissolve by dissociation, where water surrounds the separated ions. Molecular compounds interact with water, but most do NOT dissociate. Some molecular substances react with water when they dissolve. Aqueous Reactions ? 2015 Pearson Education, Inc.

Chemistry The Central Science Chapter 3

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Chapter 3 Chemical Reactions and Reaction Stoichiometry James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation ? 2015 Pearson Education, Inc. Stoichiometry The study of the mass relationships in chemistry Based on the Law of Conservation of Mass (Antoine Lavoisier, 1789) ?We may lay it down as an incontestable axiom that, in all the operations of art and nature, nothing is created; an equal amount of matter exists both before and after the experiment. Upon this principle, the whole art of performing chemical experiments depends.? ?Antoine Lavoisier ? 2015 Pearson Education, Inc. Chemical Equations Chemical equations are concise representations of chemical reactions. Stoichiometry ? 2015 Pearson Education, Inc. 3 What Is in a Chemical Equation?

Chemistry The Central Science Chapter 2

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Chapter 2Atoms, Molecules,and Ions James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation ? 2015 Pearson Education, Inc. 1 Atomic Theory of Matter The theory that atoms are the fundamental building blocks of matter reemerged in the early nineteenth century, championed by John Dalton. Atoms, Molecules, and Ions ? 2015 Pearson Education, Inc. 2 Dalton?s Postulates Each element is composed of extremely small particles called atoms. Atoms, Molecules, and Ions ? 2015 Pearson Education, Inc. 3 Dalton?s Postulates All atoms of a given element are identical to one another in mass and other properties, but the atoms of one element are different from the atoms of all other elements. Atoms, Molecules, and Ions ? 2015 Pearson Education, Inc. 4 Dalton?s Postulates

Chemistry The Central Science Chapter 1

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Chapter 1 Introduction: Matter and Measurement James F. Kirby Quinnipiac University Hamden, CT Lecture Presentation ? 2015 Pearson Education, Inc. 1 Chemistry Chemistry is the study of the properties and behavior of matter. It is central to our fundamental understanding of many science-related fields. Matter And Measurement ? 2015 Pearson Education, Inc. 2 Matter Matter is anything that has mass and takes up space. Matter And Measurement ? 2015 Pearson Education, Inc. 3 Matter Atoms are the building blocks of matter. Each element is made of a unique kind of atom. A compound is made of two or more different kinds of elements.

Chapter 1 - Chemistry, A First Course

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