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ap bio chap 8 Flashcards

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39803551metabolismThe totality of an organism's chemical reactions is called0
39803552metabolismis an emergent property of life that arises from interactions between molecules within the orderly environment of the cell.1
39803553catabolic pathwaysrelease energy by breaking down complex molecules to simpler compounds.2
39803554cellular respirationA major pathway of catabolism is _________, in which the sugar glucose is broken down in the presence of oxygen to carbon dioxide and water.3
39803555anabolic pathwaysconsume energy to build complicated molecules from simpler compounds. They are also called biosynthetic pathways.4
39803556bioenergeticsis the study of how organisms manage their energy resources5
39803557heat or thermal energyis kinetic energy associated with the random movement of atoms or molecules.6
39803558chemical energyis a form of potential energy stored in molecules because of the arrangement of their atoms.7
39805152thermodynamicsAnother way to state the second law of thermodynamics is for a process to occur spontaneously, it must increase the entropy of the universe.8
39805153systemrefers to the matter under study and the surroundings include everything outside the system9
39806284closed systemapproximated by liquid in a thermos, is isolated from its surroundings.10
39806285open systemenergy and matter can be transferred between the system and its surroundings.11
39806286first law of thermodynamicsstates that energy can be transferred and transformed, but it cannot be created or destroyed.12
39806287entropyis a quantity used as a measure of disorder or randomness13
39806288second law of thermodynamicsstates that every energy transfer or transformation increases the entropy of the universe.14
39806289spontaneousdescribes a process that can occur without an input of energy.15
39806290free energy changeThe ______________of a reaction tells us whether it is spontaneous.16
39806291free energyis the portion of a system's energy that is able to perform work when temperature and pressure is uniform throughout the system, as in a living cell.17
39806292G= H − TS, where T is temperature in Kelvin units.18
39806293free energycan be thought of as a measure of the stability of a system.19
40077513negativechange in G must be _________ for a process to be spontaneous20
40077514exergonicAn _________ reaction proceeds with a net release of free energy; G is negative.21
40077515endergonicAn __________ reaction is one that absorbs free energy from its surroundings.change in g is positive22
40077516energy couplingthe use of an exergonic process to drive an endergonic one.23
40077517ATPa type of nucleotide consisting of the nitrogenous base adenine, the sugar ribose, and a chain of three phosphate groups.24
40077518phosphorylated• In the cell, the energy from the hydrolysis of ATP is directly coupled to endergonic processes by the transfer of the phosphate group to another molecule. This recipient molecule is now25
40077519hydrolysis of ATP• Mechanical, transport, and chemical work in the cell are nearly always powered by the26
40077520phosphate group• ATP is a renewable resource that can be regenerated by the addition of a _____________ to ADP.27
40077521Catabolic________(exergonic) pathways, especially cellular respiration, provide the energy for the exergonic regeneration of ATP.28
40077522activation energyThe initial investment of energy for starting a reaction is the29
40077523transition state At the summit, the molecules are in an unstable condition, the __________30
40077524enzyme-substrate complex• The enzyme binds to a substrate, or substrates, forming an ________________31
40077525weak interactions• In most cases, substrates are held in the active site by ______________, such as hydrogen bonds and ionic bonds.32
40077526R groups________of a few amino acids on the active site catalyze the conversion of substrate to product.33
40077527microenvironment R groups at the active site may create a ______________ that is conducive to a specific reaction.34
40077528lowAt ____ substrate concentrations, an increase in substrate concentration speeds binding to available active sites.35
40077529increasesAs temperature _________, collisions between substrates and active sites occur more frequently as molecules move more rapidly.36
400775306 and 8Optimal pH falls between pH __________ for most enzymes.37
40077531cofactors• Many enzymes require nonprotein helpers, called ___________, for catalytic activity.38
40077532coenzymesOrganic cofactors are called _________39
40077533inhibitorsBinding by __________ prevents enzymes from catalyzing reactions40
40077534competitive inhibitors• Some reversible inhibitors, called ____________, resemble the substrate and compete for binding to the active site.41
40077535Noncompetitive inhibitors_____________ impede enzymatic reactions by binding to another part of the molecule.42
40077536allostericMetabolic control often depends on ________ regulation.43
40077537allosteric sitea specific receptor on the enzyme away from the active site.44
40077538activator, inhibitor• The binding of an __________ stabilizes the conformation that has functional active sites, while the binding of an __________ stabilizes the inactive form of the enzyme.45
40077539cooperativity• In enzymes with multiple catalytic subunits, binding by a substrate to one active site stabilizes favorable conformational changes at all other subunits, a process called .46
40077540feedback inhibition• A common method of metabolic control is ____________ in which an early step in a metabolic pathway is switched off by the pathway's final product.47

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