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AP Chemistry- Chapter 11 Flashcards

Intermolecular Forces

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654944751What does the state of a substance depend on ?The kinetic energy of the particles and the energy of attraction
654944752What two things can change the state of matter?Temperature and Pressure
654944753WeakerAre intermolecular forces weaker or stronger than covalent or ionic bonds?
654944754IncreasesDoes melting point increase or decrease with an increase in molar mass?
654944755Forces that are present in solutions and exist between an ion and a partial charge of a polar moleculeIon-Dipole Forces
654944756The three types of intermolecular forces are...Dipole-Dipole Forces London Dispersion Forces Hydrogen Bonding
654944757London Dispersion Forces are present between...Non-polar molecules
654944758Polarizabilityease for which an instantaneous dipole can be created - will increase with molecular size **More polarizable molecules will have greater dispersion forces***
654944759London Dispersion Forces are the only electrostatic force that are among...all molecules whether polar or nonpolar
654944760N, O, and FHydrogen Bonds occur between what three elements?
654944761ViscosityResistance of a liquid to flow
654944762CohesionSimilar molecules are attracted to one another
654944763AdhesionMolecules are attracted to the walls of their container
654944764Capillary ActionMolecules work their way up a narrow tube
654944765Phase ChangesChanges from one state to another
654944766The 3 phasesSolid, Liquid, Gas
654944767Heat of Fusionenergy required to cause the change from a solid to a liquid, denoted, deltaHoffusion
654944768Heat of Vaporizationenergy required to cause the change from a liquid to a gas, denoted, deltaHofvaporization
654944769Intermolecular AttractionsGoing from a liquid to a gas overcomes all
654944770Heat of Sublimationenergy change required for going from a solid to a gas
654944771Calculating change in enthalpy (equation)delta"H"=q(m)(c)(changeinheat) Used for ascending or descending lines
654944772Calculation enthalpy in a phase changeDELTA"h"OFFUSION X #OFMOLES
654944773Supercoolingtemporarily cooling a liquid below its freezing point without forming a solid
654944774Critical Temperaturehighest temperature where a distinct liquid phase can be formed
654944775Critical Pressurepressure needed to get a liquid at the critical temperature
654944776Vapor Pressureconstant value of the pressure of the vapor above a liquid
654944777Dynamic Equilibriumwhen two opposing processes are occurring at the same time with equal rates
654944778VolatileSubstances that evaporate readily
654944779pressureBoiling point will increase with increasing...
654944780Triple PointWhen all phases are in equilibrium
654944781Crystalline Solidatoms, ions, or molecules are arranged in a well-ordered arrangment
654944782Amorphous Solidparticles that have no ordered arrangment
654944783Unit Cellrepeating unit of a crystalline solid
654944784Primitive Cubicatoms located only at the corners, each atom will be part of 8 cubic cells
654944785Body Centeredatoms at corners and one atom in the center of the cube
654944786Face Centeredatoms at corners and one atom in the center of each face, atoms on the face are each part of two cubic cells
6549447871 centimeter = ? Angstroms10e-10
654944788Hexagonal Close packingwhen the spheres of the first and third layers are in line
654944789Cubic Close Packagingwhen the first and third layers are not in line
654944790Coordination Numbernumber of particles immediately surrounding a particle in a crystal Usually 12
654944791Molecular SolidsSoft, low melting points. Gases and liquids at room temperatures
654944792Covalent NetworkHarder and higher melting points that molecular solids
654944793Ionic SolidsStrength and melting point are dependent upon charge
654944794Metallic SolidsMade of metal atoms. stronger bonding than intermolecular forces. Delocalized electrons

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