1919775329 | units for k are M * s⁻¹ | zero order rxn | 0 | |
1919775330 | [A] = -kt + [A]₀ | integrated rate law for zero order rxn | 1 | |
1919775331 | [A] vs. time straight line plot | zero order rxn | 2 | |
1919775332 | t₁/₂ = [A]₀/2k | half life for zero order rxn | 3 | |
1919775333 | units for k in s⁻¹ (1/s) | 1st order rxn | 4 | |
1919775334 | ln[A] = -kt + ln[A]₀ | integrated rate law for 1st order rxn | 5 | |
1919775335 | ln[A] vs. time Straight Plot | 1st order rxn | 6 | |
1919775336 | t₁/₂ = ln 2/k | half life for 1st order rxn | 7 | |
1919775337 | units for k in M ⁻¹ * s⁻¹ | 2nd order rxn | 8 | |
1919775338 | 1/[A] = kt + 1/[A]₀ | integrated rate law for 2nd order rxn | 9 | |
1919775339 | 1/[A] vs. time Straight Plot | 2nd order rxn | 10 | |
1919775340 | t₁/₂ = 1/k[A]₀ | half life for 2nd order rxn | 11 | |
1919775341 | Activation Energy | the kinetic energy that reactant molecules must have to so that a reaction can occur. | 12 | |
1919775342 | Arrhenius Equation | An equation that relates the specific rate constant to activation energy and temperature. | 13 | |
1919775343 | Catalyst | A substance that increases the rate at which a reaction occurs. It remains unchanged when the reaction is complete. | 14 | |
1919775344 | Collision Theory | A theory of reaction rates that states that effective collisions between reactant molecules must take place for reaction to occur. | 15 | |
1919775345 | Effective Collision | A collision between molecules that results in reaction; one in which molecules collide with proper orientations and with sufficient energy to react. | 16 | |
1919775346 | Elementary Step | An individual step in the mechanism by which a reaction occurs. The reaction order for this step matches the reactant coefficients. | 17 | |
1919775347 | Enzyme | A protein that acts as a catalyst in a biological system. | 18 | |
1919775348 | Half-life of a Reactant | The time required for half of that reactant to be converted into product(s). | 19 | |
1919775349 | Integrated Rate Equation | An equation that relates the concentration of a reactant remaining to the time elapsed; has different mathematical forms for different orders of reaction. | 20 | |
1919775350 | Method of Initial Rates | A method of determining the rate-law expression by carrying out a reaction with different initial concentrations and analyzing the resulting changes in initial rates. | 21 | |
1919775352 | Rate Constant | rate=k[A]^x[B]^y. An experimentally-determined constant that is different for different reactions and that, for a given reaction, changes only with temperature or the presence of a catalyst; "k" in the rate-law expression, | 22 | |
1919775353 | Rate- determining Step | The slowest elementary step in a reaction mechanism; the step that limits the overall rate of reaction. | 23 | |
1919775354 | Rate Law | An equation that relates the rate of a reaction to the concentrations of the reactants and the specific rate constant; rate=k[A]^x[B]^y. Must be determined from experimental data. | 24 | |
1919775355 | Rate of Reaction | The change in concentration of a reactant or product per unit of time. (units are M / s ) | 25 | |
1919775356 | Intermediate | A species that is produced and then entirely consumed during a multistep reaction; usually short-lived. | 26 | |
1919775357 | Reaction Mechanism | The sequence of fundamental steps by which reactants are converted into products. | 27 | |
1919775358 | Thermodynamically favorable, spontaneous reaction | A reaction that occurs with a net release of free energy, G; a reaction for which deltaG is negative. | 28 | |
1919775359 | Transition state | A relatively high-energy state in which bonds in reactant molecules are partially broken and new ones are partially formed. | 29 | |
1919775360 | Transition State Theory | A theory of reaction rates that states that reactants pass through high-energy transition states before forming products. | 30 |
AP Chemistry Chpt 12: Kinetics Flashcards
Primary tabs
Need Help?
We hope your visit has been a productive one. If you're having any problems, or would like to give some feedback, we'd love to hear from you.
For general help, questions, and suggestions, try our dedicated support forums.
If you need to contact the Course-Notes.Org web experience team, please use our contact form.
Need Notes?
While we strive to provide the most comprehensive notes for as many high school textbooks as possible, there are certainly going to be some that we miss. Drop us a note and let us know which textbooks you need. Be sure to include which edition of the textbook you are using! If we see enough demand, we'll do whatever we can to get those notes up on the site for you!