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AP CHEMISTRY Flashcards

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4205895041John Dalton's atomic theory1. All matter is made up of atoms (T) 2. Atoms of a given element are identical in size and mass (F- isotopes) 3. Atoms can't be subdivided, created, or destroyed (F- protons, neutrons, and electrons) 4. Atoms combine in single whole-number ratios (T) 5. Atoms are combined, rearranged, or separated to form compounds (T)0
4205847184Henry Becquerel (1896)Accomplishment: observed radioactive decay of U Significance: atoms are not unchangeable1
4205849652J. J. Thompson (1897)Accomplishment: discovered electrons by experimenting with the Cathode Ray Tube Significance: atoms are not indivisible2
4205900363Goldstein (1886)While experimenting with Cathode Ray tube, he discovered the presence of protons3
4205851420Max Plank (1900)Accomplishment: studied blackbody radiation Significance: proposed the quantinization of energy4
4205852786Albert Einstein (1905)Accomplishment: examined light-metal interaction Significance: photoelectric effect: light behaves like particles5
4205854493Ernest Rutherford (1908; 1911)Accomplishment: studied radioactive emissions; used alpha radiation to bombard Au (gold) Significance: named alpha, beta, and gamma radiation; discovered nucleus6
4205856762Robert Milikan (1908)Accomplishment: measured electron charge Significance: determined an electron's mass (1/2000 of mass of a proton)7
4205862170Henry Moseley (1913)Accomplishment: studied x-ray spectra of atoms Significance: defined atomic number8
4205863309Neils Bohr (1913)Accomplishment: investigated atomic spectra Significance: proposed quantized levels9
4205865571Louis deBroglie (1924)Accomplishment: theoretician Significance: proposed matter exhibits wave-like behavior10
4205868125Werner Heisenberg (1927)Accomplishment: did theoretical work Significance: developed Uncertainty principle11
4205869572Erwin Schrodinger (1926)Accomplishment: did calculations on the H atom Significance: developed the wave equation12
4205871078James Chadwick (1932)Accomplishment: studied nucleus Significance: discovered the neutron13
4205876311atomic numberthe number of protons in the nucleus14
4205876322atomic massthe total number of protons and neutrons15
4205884137isotopeselements with the same atomic number but different atomic masses (different number of neutrons)16
4205892912average atomic weight of an element(exact weight of isotope #1)(abundance of isotope #1) + (exact weight of isotope #2)(abundance of isotope #2)17
4205888021mass spectrometrytechnique in which gaseous atoms are bombarded with high energy electrons which removes one or more electrons from an atom to form positive ions that can be separated according to their masses when subjected to a magnetic field18
4205910800Relationship between speed of light, wavelength, and frequencyc = λv (c- 2.998*10^8 m/s; λ- wavelength; v- frequency)19
4205913122Relationship between energy of photon and frequencyE = hv (E- energy of photon; h- Plank's constant (6.636*10^-34 Js); v- frequency)20
4205918767Coulomb's Lawcalculates the force between two particles F = q1q2/r^2 F- force between two particles; q1, q2- charges; r- distance separating them21
4205925695nprincipal quantum number which indicates distance from nucleus; possible values: 1, 2, 3...22
4205927233lorbital quantum number which indicates sublevel (s, p, d, f); possible values: 0, 1, 2... (n-1)23
4205928843m1magnetic quantum number which indicates orbital orientation; possible values: 0, ±1, ±2...(±l)24
4205932305msspin quantum number which indicates whether the spin is clockwise or anti-clockwise; possible values: ±1/225
4205934078Aufbau principle26
4205943401Effective nuclear charge (Zeff)the actual charge an electron feels because of the nuclear charge cancelation by electrons in the same principle energy level (cancels fraction of charge) and core electrons (cancels full nuclear charge) Zeff = Z - S (Z- atomic number; S- number of shielding electrons)27
4205947141Shielding effectdescribes balance between the pull of protons and the repulsion from core electrons28
4205951489Atomic Radiusthe distance between the nuclei of adjacent atoms in an element Trend: INCREASES DOWN the periodic table (PT) because of the increase in principal energy levels and DECREASES ACROSS (left to right) because the electrons in the same principal energy level are attracted to nuclei with greater Zeff29
4205956010Ionization Energythe energy required to pull one electron away from a gaseous atom Trend: DECREASES DOWN the PT because of increasing number of energy levels and the greater shielding effect and INCREASES ACROSS because of the increase in attractions to more highly charged nuclei Exceptions: Group 13 (B, Al, Ga, Zn, Tl) because the outermost electron occupies the p sublevel Group 16 (O, S, Se, Te, Po) fourth electron in p sublevel is paired30
4205961259Electron Affinitythe energy released when a gaseous atom gains an electron to form a negative ion Trend: DECREASES DOWN the PT because of the attraction between the nucleus and the added electrons becomes smaller with the increasing distance between the electrons and the nucleus and INCREASES ACROSS the PT Exceptions: Al, Si, P, S, Cl have higher electron affinities than those above them because of the greater electron repulsion present in the smaller atoms31

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