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AP Chemistry Review Flashcards

Comprehensive review of AP Chemistry concepts and terminology in preparation for AP test

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1619227166critical pointtemperature-pressure point after which gas can no longer form liquid0
1619227167triple pointtemperature-pressure combination at which solid, liquid, and gas states appear1
1619227168sublimationphase change from solid to gas2
1619227169depositionphase change from gas to solid3
1619227170solid CO2chemical composition of dry ice4
1619227171equilibriumhappens at lines in phase change charts5
1619227172London dispersion forcesuniversal IMF for nonpolar molecules6
1619227173Dipole-dipole forcesIMF that exists in polar molecules7
1619227174Hydrogen bondingIMF that occurs with FON8
1619227175effects of IMFboiling point, melting point, viscosity, vapor pressure, surface tension9
1619227176viscositythickness10
1619227177vapor pressurestronger IMF= lower... weaker IMF= higher...11
1619227178N=N.(0.5)^time/time half-lifehalf-life equation12
1619227179octahedralAX613
1619227180square pyramidalAX5E14
1619227181square planarAX4E215
1619227182trigonal bipyramidalAX516
1619227183see-sawAX4E17
1619227184T-shapeAX3E218
1619227185methods of increasing rateraising heat, adding catalyst, heighten concentration, bigger surface area19
1619227186∆Hvapenergy needed to vaporize a mole of a liquid20
1619227187boiling pointpoint at which vapor pressure=air pressure above21
1619227188fusionmelting22
1619227189London dispersion forceslarger molecules which have higher mass and therefore electron density have stronger...23
1619227190bond energyenergy needed to break a bond24
1619227191always∆H | ∆S is spontaneous... - | +25
1619227192at low temperatures∆H | ∆S is spontaneous... - | -26
1619227193at high temperatures∆H | ∆S is spontaneous... + | +27
1619227194never∆H | ∆S is spontaneous... + | -28
1619227195+ ∆Sgreater # of moles of gas formed and greater volume formed cause...29
1619227196+ ∆Sgas > liquid > solid and (aq)>(s) cause...30
1619227197+ ∆Sdiatomic molecules forming mixed molecules, e.g. H2 + I2 -> 2HI, means...31
1619227198adiabaticchange without heat transfer between the system and its surroundings32
1619227199isothermalchange that occurs at constant temperature33
1619227200heat capacityamount of heat needed to change a system by 1˚C34
1619227201specific heatheat needed to change 1 g of substance to 1˚C35
16192272024.184specific heat of water36
1619227203ionic... compounds are most conductive37
1619227204-ous acidif anion ends in -ite, acid name ends in...38
1619227205-ic acidif anion ends in -ate, acid name ends in...39
1619227206hydro-ic acidif anion ends in -ide, acid name ends in40
1619227207Balmer Seriesspectrum of light when an electron drops to energy level n=241
1619227208redwhen n=3 ->2, color=42
1619227209blue-greenwhen n=4 ->2, color=43
1619227210blue-violetwhen n=5 ->2, color=44
1619227211violetwhen n=6 ->2, color=45
1619227212n (first quantum number)variable for energy of e-, goes from 1,2,3 on up46
1619227213l (second quantum number)variable for type of orbital47
1619227214sl=048
1619227215pl=149
1619227216dl=250
1619227217fl=351
1619227218m (third quantum number)variable for orientation of orbital (-1 through +1)52
1619227219s (fourth quantum number)variable for spin of electron (+.5 or -.5)53
1619227220s orbitalsthese orbitals are spherical54
1619227221p orbitalsthese orbitals are perpendicular55
1619227222d orbitalsthese orbitals are diagonal56
1619227223electron affinityenergy involved in gaining an electron to become a negative ion57
1619227224C + 273calculation from K to C58
1619227225Boltzmann distributionstates molecules at a given temp. vary in kinetic energy along a bell-curve of molecular velocities59
1619227226Diffusionmixing of gases60
1619227227Effusionpassage of gas through tiny orifice61
1619227228moles solute/kg solventmolality =62
1619227229g solute/g solvent x 100mass percent63
1619227230likelike dissolves...64
1619227231entropy (S)degree of disorder in a system65
1619227232increasingentropy in the universe is always...66
1619227233spontaneousIf K>1, then Gº<0 and reaction will be...at chemical equilibrium67
1619227234not spontaneousIf K<1, then Gº>0 and reaction will be...at chemical equilibrium68
1619227235meth-(organics) one carbon69
1619227236eth-(organics) two carbons70
1619227237prop-(organics) three carbons71
1619227238but-(organics) four carbons72
1619227239pent-(organics) five carbons73
1619227240hex-(organics) six carbons74
1619227241hept-(organics) seven carbons75
1619227242oct-(organics) eight carbons76
1619227243non-(organics) nine carbons77
1619227244dec-(organics) ten carbons78
1619227245rate lawthis MUST be determined experimentally79
1619227246zero[A] vs. time is a ...-order reaction80
1619227247firstln[A] vs. time is a ...-order reaction81
1619227248second1/[A] vs. time is a ...-order reaction82
1619227249thirdAP doesn't deal with ...-order reaction, don't pick it!83
1619227250activated complex (transition state)peak of energy diagram84
1619227251Arrhenius equationto find activation energy use the...85
1619227252k=Ae^(-Ea/RT)Arrhenius equation86
1619227253ln (k1/k2) = (Ea/R)(1/T2-1/T1)equation to find Ea from reaction rate constants at two different temperatures87
1619227254hydrocarbonscarbon & hydrogen compounds88
1619227255carbohydratescarbon, hydrogen, oxygen compounds89
1619227256alkane(organics) single-bonded compound90
1619227257alkene(organics) double-bonded compound91
1619227258alkyne(organics) triple-bonded compound92
1619227259alcoholorganic w/ -OH group93
1619227260etherorganic w/ -O-94
1619227261amineorganic w/ -NH295
1619227262-anolending for alcohols96
1619227263geometric isomerstwo molecules with identical connectivity but different geometries97
1619227264condensationorganic reaction in which two functional groups come together, resulting in the release of water98
1619227265hydrolysisorganic reaction in which water breaks apart a molecule (splitting into two hydroxides)99
1619227266Ag+, Pb2+, Hg2+all cations are soluble with bromide, chloride and iodide EXCEPT100
1619227267Ag+, Pb2+, Hg2+, Sr2+, Ca2+, Ba2+all cations are soluble with sulfate EXCEPT101
1619227268insolublehydroxides are soluble or insoluble?102
1619227269phosphate, sulfide, carbonate, sulfategenerally insoluble anions (names)103
1619227270allotropedifferent form of same element104
1619227271redcolor of Li (flame test)105
1619227272red/orangecolor of Ca (flame test)106
1619227273redcolor of Sr (flame test)107
1619227274yellowcolor of Na (flame test)108
1619227275green/yellowcolor of Ba (flame test)109
1619227276bluecolor of Cs (flame test)110
1619227277purplecolor of K (flame test)111
1619227278-anoic acidcarboxylic acid ending112
1619227279Amino-amine prefix113
1619227280-analaldehyde suffix114
1619227281-anoneketone suffix115
1619227282methoxy-ether prefix116
1619227283-anoateester suffix117
1619227284base and hydrogen gaspure metal or metal hydride + H20 ->118
1619227285basemetal oxide + H20 ->119
1619227286acidnonmetal oxide + H2O ->120
1619227287oxide gas and wateroxoacid solution (such as HSO4-) forms...121
1619227288complex ionstransition metals with ammonia, hydroxide, cyanide or thiocyanate form...122
16192272890∆Hº of pure elements=123
1619227290diamagneticelements which have all electrons paired and relatively unaffected by magnetic fields124
1619227291paramagneticelements which have unpaired electrons and highly affected by magnetic fields125

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