AP Notes, Outlines, Study Guides, Vocabulary, Practice Exams and more!

AP Chemistry Vocabulary Terms Flashcards

Terms : Hide Images
9627396816Accuracythe agreement of a particular value with a true value0
9627396817Acida substance that produces hydrogen ions in solution; a proton donor1
9627396818Acid-base indicatora substance that marks the end point of an acid-base titration by changing color2
9627396819Acid raina result of air pollution by sulfur dioxide3
9627396820Acidic oxidea covalent oxide that dissolves in water to give an acidic solution4
9627396821Actinide seriesa group of 14 elements following actinium in the periodic table, in which the 5f orbitals are being filled5
9627396822Activated complex (transition state)the arrangement of atoms found at the tope of the potential energy barrier as a reaction proceeds from reactants to products6
9627396823Activation energythe threshold energy that must be overcome to produce a chemical reaction7
9627396824Addition polymerizationa type of polymerization in which the monomers simply add together to form the polymer, with no other products8
9627396825Addition reactiona reaction in which atoms add to a carbon-carbon multiple bond9
9627396826Adsorptionthe collection of one substance on the surface of another10
9627396827Air pollutioncontamination of the atmosphere, mainly by the gaseous products of transportation and production of electricity11
9627396828Alcoholan organic compound in which the hydroxyl group is a substituent on a hydrocarbon12
9627396829Aldehydean organic compound containing the carbonyl group bonded to at least one hydrogen atom13
9627396830Alkali metala Group 1A metal14
9627396831Alkaline earth metala Group 2A metal15
9627396832Alkanea saturated hydrocarbon with the general formula C(n)H(2n+2)16
9627396833Acid dissociation constant (Ka)the equilibrium constant for a reaction in which a proton is removed from an acid by H2O to form the conjugate base and H3O+17
9627396834Alkenean unsaturated hydrocarbon containing a carbon-carbon double bond. The general formula is C(n)H(2n)18
9627396835Alkynean unsaturated hydrocarbon containinga triple carbon-carbon bond. The general formula is C(n)H(2n-2)19
9627396836Alloya substance that contains a mixture of elements and has metallic properties20
9627396837Alloy steela form of steel containing carbon plus other metals such as chromium, cobalt, manganese, and molybdenum21
9627396838Alpha (α) particlea helium nucleus22
9627396839Alpha-particle productiona common mode of decay for radio-active nuclides in which the mass number changes23
9627396840Aminean organic base derived from ammonia in which one or more of the hydrogen atoms are replaced by organic groups24
9627396841α-Amino acidan organic acid in which an amino group and an R group are attached to the carbon atom next to the carboxyl group25
9627396842Amorphous solida solid with considerable disorder in its structure26
9627396843Amperethe unit of electric current equal to one coulomb of charge per second27
9627396844Amphoteric substancea substance that can behave either as an acid or as a base28
9627396845Angular momentum quantum number (ℓ)the quantumnumber relating to the shape of an atomicorbital, which can assume any integral value from 0 to 'n-1' for each value of 'n'29
9627396846Aniona negative ion30
9627396847Anodethe electrode in a galvanic cell at which oxidation occurs31
9627396848Antibonding molecular orbitalan orbiting higher in energy than the atomic orbitals of which it is composed32
9627396849Aqueous solutiona solution in which water is the dissolving medium or solvent33
9627396850Aromatic hydrocarbonone of a special class of cyclic unsaturated hydrocarbons, the simplest of which is benzene34
9627396851Arrhenius concepta concept postulating that acids produce hydrogen ions in aqueous solution, while bases produce hydroxide ions35
9627396852Arrhenius equationthe equation representing the rate constant as k = Ae^[-(E[a])/(RT)], where A represents the product of the collision frequency and the steric factor, and e^[-(E[a])/(RT)] is the fraction of collisions with sufficient energy to product a reaction36
9627396853Atmospherethe mixture of gases that surrounds the earth's surfaces37
9627396854Atomic numberthe number of protons in the nucleus of an atom38
9627396855Atomic radiushalf the distance between thenuclei in a molecule consisting of identical atoms39
9627396856Atomic solida solid that contains atoms at the lattice points40
9627396857Atomic weightthe weighted average mass of the atoms in a naturally occuring element41
9627396858Aufbau principlethe principle stating that as protons are added one by one to the nucleus to build up the elements, electrons are similarly added to hydrogen-like orbitals42
9627396859Autoionizationthe transfer of a proton from one molecule to another of the same substance43
9627396860Avogadro's lawequal volumes of gases at the same temperature and pressure contain the same number of particles44
9627396861Avogadro's numberthe number of atoms in exactly 12 grams of pure ^(12)C, equal to 6.022 x 10^(23)45
9627396862Ball-and-stick modela molecular model that distorts the sizes of atoms but shows bond relationships clearly46
9627396863Band modela molecular model for metals in which the electrons are assumed to travel around the metal crystal in molecular orbitals formed from the valence atomic orbitals of the metal atoms47
9627396864Barometera device for measuring atmospheric pressure48
9627396865Basea substance that produces hydroxide ions in aqueous solution, a proton acceptor49
9627396866Basic oxidean ionic oxide that dissolves in water to produce a basic solution50
9627396867Basic oxygen processa process for producing steel by oxidizing and removing the impurities in iron using a high-pressure blast of oxygen51
9627396868Batterya group of galvanic cells connected in series52
9627396869Beta (β) particlean electron produced in radioactivedecay53
9627396870Beta-particle productiona decay process for radioactive nuclides in which the mass number remains constant and the atomic number changes. The net effect is to change a neutron to a proton54
9627396871Bidentate liganda ligand that can form two bonds to a metal ion55
9627396872Bimolecular stepa reaction involving the collision of two molecules56
9627396873Binary compounda two-element compound57
9627396874Binding energy (nuclear)the energy required to decompose a nucleus into its component nucleus58
9627396875Biomoleculea molecule responsible for maintaining and/or reproducing life59
9627396876Bond energythe energy required to break a given chemical bond60
9627396877Bond lengththe distance between the nuclei of the two atoms connected by a bond; the distance where the total energy of a diatomic molecule is minimal61
9627396878Bond orderthe difference between the number of bonding electrons and the number of antibonding electrons, divided by two. It is an index of bond strength62
9627396879Bonding molecular orbitalan orbital lower in energy than the atomic orbitals or which it is composed63
9627396880Bonding pairan electron pair found in the space between two atoms64
9627396881Boranea covalent hydride of boron65
9627396882Boyle's lawthe volume of a given sample of gas at constant temperature varies inversely with the pressure66
9627396883Brønsted-Lowry modela model proposing that an acid is a proton donor, and a base is a proton acceptor67
9627396884Buffered solutiona solution that resists a changein its pH when either hydroxide ions or protons are added68
9627396885Buffering capacitythe ability of a buffered solution to absorb protons or hydroxide ions without a significant change in pH; determined by the magnitudes of [HA] and [A-] in the solution69
9627396886Calorimetrythe science of measuring heat flow70
9627396887Capillary actionthe spontaneous rising of a liquid in a narrow tube71
9627396888Carbohydratea polyhydroxyl ketone or polyhydroxyl aldehyde or a polymer composed of these72
9627396889Carbon steelan alloy of iron containing up to about 1.5% carbon73
9627396890Carboxyl groupthe -COOH group in an organic acid74
9627396891Carboxylic acidan organic compound containing the carboxyl group; an acid with the general formula RCOOH75
9627396892Catalysta substance that speeds up a reaction without being consumed76
9627396893Cathodethe electrode in a galvanic cell at which reduction occurs77
9627396894Cathode raysthe "rays" emanating from the negative electrode (cathode) in a partially evacuated tube; a stream of electrons78
9627396895Cationa positive ion79
9627396896Cell potential (electromotive force)the driving force in a galvanic cell that pulls electrons from the reducing agent in one compartment to the oxidizing agent in the other80
9627396897Chain reaction (nuclear)a self-sustaining fission process caused by the production or neutrons that proceed to split other nuclei81
9627396898Charles' lawthe volume of a given sample of gas at constant pressure is directly proportional to the temperature in kelvins82
9627396899Chelating ligand (chelate)a ligand having more than one atom with a long pair that can be used to bond to a metal ion83
9627396900Chemical bondthe force or, more accurately, the energy, that holds two atoms together in a compound84
9627396901Chemical changethe change of substances into other substances through a reorginzation of the atoms; a chemical reaction85
9627396902Chemical equationa representation of a chemical reaction showing the relative numbers of reactant and product molecules86
9627396903Chemical equilibriuma dynamic reaction system in which the concentrations of all reactants and products remain constant as a function of time87
9627396904Chemical formulathe representation of a molecule in which the symbols for the elements areused to indicate the types of atoms present and subscripts are used to show the relative numbers of atoms88
9627396905Chemical kineticsthe area of chemistry that concerns reaction rates89
9627396906Chemical stoichiometrythe calculation of the quantities of material consumed and produced in chemical reactions90
9627396907Chromatographythe general name for a series of methods for separating mixtures by employing a system with a mobile phase and a stationary phase91
9627396908colligative propertiesproperties of solution that depend only on the number, and not on the identity, of the solute particles92
9627396909collision modelmodel based on idea that molecules must collide to react; used to account for the observed characteristics of reaction rates93
9627396910coagulationdestruction of colloid by causing particles to aggregate and settle out94
9627396911combustion reactionvigorous and exothermic reaction that takes place between certain substances, particularly organic compounds, and oxygen95
9627396912common ion effectshift in equilibrium position caused by addition or presence of ion involved in equilibrium reaction96
9627396913complete ionic equationequation that shows all substances that are strong electrolytes as ions97
9627396914complex ioncharged species consisting of metal ion surrounded by ligands98
9627396915compoundsubstance with constant composition that can be broken down into elements by chemical processes99
9627396916concentration cellgalvanic cell in which both compartments contain the same components, but at different concentrations100
9627396917condensationprocess by which vapor molecules reform a liquid101
9627396918condensation polymerizationtype of polymerization in which the formation of a small molecule, such as water, accompanies the extension of the polymer chain102
9627396919condensation reactionreaction in which two molecules are joined, accompanied by the elimination of a water molecule103
9627396920condensed states of matterliquids and solids104
9627396921conjugate acidspecies formed when proton is added to base105
9627396922conjugate acid-base pairtwo species related to each other by the donating and accepting of a single proton106
9627396923conjugate basewhat remains of an acid molecule after a proton is lost107
9627396924continuous spectrumspectrum that exhibits all the wavelengths of visible light108
9627396925control rodsrods in nuclear reactor composed of substances that absorb neutrons. these rods regulate the power level of the reactor109
9627396926coordinate covalent bondmetal-ligand bond resulting from the interaction of a lewis base (ligand) and a lewis acid (metal ion)110
9627396927coordination compoundcompound composed of complex ion and counter ions sufficient to give no net charge111
9627396928coordination isomerismisomerism in coordination compound in which the composition of the coordination sphere of a metal ion varies112
9627396929coordination numbernumber of bonds formed between the metal ion and the ligands in a complex ion113
9627396930core electroninner electron in an atom114
9627396931corrosionprocess by which metals are oxidized in the atmosphere115
9627396932Coulomb's LawE= 2.31 x 10^-19 (Q1Q2/r), where E is the energy of interaction between a pair of ions, expressed in joules; r is the distance between the ion centers in nm; and Q1 and Q2 are the numerical ion charges116
9627396933counterionsanions or cations that balance the charge on the complex ion in a coordination compound117
9627396934covalent bondingtype of bonding in which electrons are shared by atoms118
9627396935critical massmass of fissionable material required to produce a self-sustaining chain reaction119
9627396936critical pointpoint on a phase diagram at which the temperature and pressure have their critical values; the end point of the liquid-vapor line120
9627396937critical temperaturetemperature above which vapor cannot be liquefied no matter what pressure is applied121
9627396938crystalline solidsolid with a regular arrangement of its components122
9627396939Dalton's law of partial pressuresfor a mixture of gases in a container, the total pressure exerted is the sum of the pressures that each gas would exert if it were alone123
9627396940degenerate orbitalsgroup of orbitals with the same energy124
9627396941densityproperty of matter representing the mass per unit volume125
9627396942deoxyribonucleic acid (DNA)huge nucleotide polymer having a double-helical structure with complementary bases on the two strands. its major functions are protein synthesis and the storage and transport of genetic information126
9627396943desalinationremoval of dissolved salts from an aqueous solution127
9627396944dialysisphenomenon in which a semipermeable membrane allows transfer of both solvent molecules and small solute molecules and ions128
9627396945diamagnetismtype of magnetism, associated with paired electrons, that causes a substance to be repelled from the inducing magnetic field129
9627396946differential rate lawexpression that gives the rate of a reaction as a function of concentrations; often called rate law130
9627396947diffusionmixing of gases131
9627396948dilutionprocess of adding solvent to lower the concentration of solute in a solution132
9627396949dimermolecule formed by the joining of two identical monomers133
9627396950dipole-dipole attractionattractive force resulting when polar molecules line up so that the positive and negative ends are close to each other134
9627396951dipole momentproperty of a molecule whose charge distribution can be represented by a center of positive charge and a center of negative charge135
9627396952distillationmethod for separating the components of a liquid mixture that depends on differences in the ease of vaporization of the components136
9627396953double bondbond in which two pairs of electrons are shared by two atoms137
9627396954dry cell batterycommon battery used in calculators, watches, radios, and tape players138
9627396955effusionpassage of a gas through a tiny orifice into an evacuated chamber139
9627396956electrical conductivityability to conduct an electric current140
9627396957electrochemistrystudy of the interchange of chemical and electrical energy141
9627396958electrolysisprocess that involves forcing a current through a cell to cause a nonspontaneous chemical reaction to occur142
9627396959electrolytematerial that dissolves in water to give a solution that conducts an electric current143
9627396960electrolytic cellcell that uses electrical energy to produce a chemical change that would otherwise not occur spontaneously144
9627396961electromagnetic radiationradiant energy that exhibits wavelike behavior and travels through space at the speed of light in a vacuum145
9627396962electrona negatively charged particle that moves around the nucleus of an atom146
9627396963electron affinitythe energy change associated with the addition of an electron to a gaseous atom147
9627396964electron spin quantum numbera quantum number representing one of the two possible values for the electron spin; either +(1/2) or -(1/2)148
9627396965electronegativitiythe tendency of an atom in a molecule to attract shared electrons to itself149
9627396966elementa substance that cannot be decomposed into simpler substances by chemical or physical means150
9627396967electron capturea process in which one of the inner-orbital electrons in an atom is captured by the nucleus151
9627396968elementary stepa reaction whose rate law can be written from its molecularity152
9627396969empirical formulasimplest whole number ratio of atoms in a compound153
9627396970endpointpoint in a titration at which the indicator changes color154
9627396971endothermicrefers to a reaction where energy (as heat) flows into the system155
9627396972energythe capacity to do work or to cause heat flow156
9627396973enthalpyproperty of a system equal to E+PV, where E is the internal energy of the system, P is the pressure of the system, and V is the volume of the system157
9627396974enthalpy (heat) of fusionthe enthalpy change that occurs to melt a solid at its melting point158
9627396975entropya thermodynamic function that measures randomness or disorder159
9627396976enzymea large molecule, usually a protein, that catalyzes biological reactions160
9627396977equilibrium constantvalue obtained when equilibrium concentrations of the chemical species are substituted in the equilibrium expression161
9627396978equilibrium expressionthe expression obtained by multiplying the product concentrations and dividing by the multiplied reactant concentrations, with each concentration raised to a power represented by the coefficient in the balanced equation162
9627396979equilibrium pointposition where the free energy of a reaction system has its lowest possible value163
9627396980equilibrium positionparticular set of equilibrium concentrations164
9627396981equivalence point (stoichiometric point)point in a titration when enough titrant has been added to react exactly with the substance in solution being titrated165
9627396982esteran organic compound produced by the reaction between a carboxylic acid and an alcohol166
9627396983exothermicreaction where energy (as heat) flows out of the system167
9627396984faradayconstant representing the charge on one mole of electrons; 96,485 coulombs168
9627396985filtrationmethod for separating the components of a mixture containing a solid and a liquid169
9627396986first law of thermodynamicsenergy of the universe is constant170
9627396987fissionprocess of using a neuron to split a heavy nucleus into two nuclei with smaller mass numbers171
9627396988fossil fuelcoal, petroleum, or natural gas; consists of carbon-based molecules derived from decomposition of once-living organisms172
9627396989free energythermodynamic function equal to the enthalpy (H) minus the product of the entropy (S) and the Kelvin temperature (T); G=H-TS173
9627396990frequencynumber of waves (cycles) per second that pass a given point in space174
9627396991fuel cellgalvanic cell for which the reactants are continuously supplied175
9627396992functional groupatom or group of atoms in hydrocarbon derivatives that contains elements in addition to carbon and hydrogen176
9627396993fusionprocess of combining two light nuclei to form a heavier, more stable nucleus177
9627396994galvanic celldevice in which chemical energy from a spontaneous redox reaction is changed to electrical energy that can be used to do work178
9627396995galvanizingprocess in which steel is coated with zinc to prevent corrosion179
9627396996gamma (γ) rayhigh-energy photon180
9627396997geometrical (cis-trans) isomerismisomerism in which atoms or groups of atoms can assume different positions around a rigid ring or bond181
9627396998glass electrodeelectrode for measuring pH from the potential difference that develops when it is dipped into an aqueous solution containing H+ ions182
9627396999Graham's law of effusionrate of effusion of a gas is inversely proportional to the square root of the mass of its particles183
9627397000ground statelowest possible energy state of an atom or molecule184
9627397001group (of the periodic table)vertical column of elements having the same valence electron configuration and showing similar properties185
9627397002half-life (of a reactant)time required for a reactant to reach half of its original concentration186
9627397003half-life (of a radioactive sample)time required for the number of nuclides in a radioactive sample to reach half of the original value187
9627397004half-reactionstwo parts of an oxidation-reduction reaction, one representing oxidation, the other reduction188
9627397005halogenGroup 7A element189
9627397006heatenergy transferred between two objects due to a temperature difference between them190
9627397007heat capacityamount of energy required to raise the temperature of an object by one degree Celsius191
9627397008heat of fusionenthalpy change that occurs to melt a solid at its melting point192
9627397009heat of vaporizationenergy required to vaporize one mole of a liquid at a pressure of one atmosphere193
9627397010heating curveplot of temperature vs. time for a substance where energy is added at a constant rate194
9627397011heisenberg uncertainty principlea principal stating that there is a fundamental limitation to how precisely both the position and momentum of a particle can be known at a given time195
9627397012henry's lawamount of a gas dissolved in a solution is directly proportional to the pressure of the gas above the solution196
9627397013hess's lawin going from a particular set of reactants to a particular set of products, the enthalpy change is the same whether the reaction takes place in one step or in a series of steps197
9627397014heterogeneous equilibriumequilibrium involving reactants and/or products in more than one phase198
9627397015homogeneous equilibriumequilibrium system where all reactants and products are in the same phase199
9627397016hund's rulelowest energy configuration for an atom is the one having the maximum number of unpaired electrons allowed by the Pauli exclusion principle in a particular set of degenerate orbitals, with all unpaired electrons having parallel spins200
9627397017hybrid orbitalsset of atomic orbitals adopted by an atom in a molecule different from those of the atom in the free state201
9627397018hybridizationmixing of the native orbitals on a given atom to form special atomic orbitals for bonding202
9627397019hydrationinteraction between solute particles and water molecules203
9627397020hydridebinary compound containing hydrogen204
9627397021hydrocarboncompound composed of carbon and hydrogen205
9627397022hydrogen bondingunusually strong dipole-dipole attractions that occur among molecules in which hydrogen is bonded to a highly electronegative atom206
9627397023hydronium ionthe H3O+ ion; a hydrated proton207
9627397024hypothesisone or more assumptions put forth to explain the observed behavior of nature208
9627397025ideal gas lawequation of state for a gas, where the state of the gas is its condition at a given time; expressed by PV=nRT, where P is pressure, V is volume, n is moles of the gas, R is the universal gas constant, and T is absolute temperature209
9627397026ideal solutionsolution whose vapor pressure is directly proportional to the mole fraction of solvent present210
9627397027indicatorchemical that changes color and is used to mark the end point of a titration211
9627397028integrated rate lawexpression that shows concentration of reactant as function of time212
9627397029intermediatespecies that is neither a reactant nor a product but that is formed and consumed in the reaction sequence213
9627397030intermolecular forcesrelatively weak interactions that occur between molecules214
9627397031internal energyproperty of system that can be changed by a flow of work, heat, or both; ΔE= q+w, where ΔE is the change in the internal energy of the system, q is heat, and w is work215
9627397032ionatom or group of atoms that has a net positive or negative charge216
9627397033ion- product (dissociation) constant (Kw)equilibrium constant for the auto-ionization of water; Kw= [H+][OH-]. at 25°C, Kw equals 1.0x10^-14217
9627397034ionic bondingelectrostatic attraction between oppositely charged ions218
9627397035ionic compound (binary)compound that results when a metal reacts with a nonmetal to form a cation and an anion219
9627397036ionic solid (salt)solid containing cations and anions that dissolves in water to give a solution containing the separated ions which are mobile and thus free to conduct electrical current220
9627397037isoelectronic ionsions containing the same number of electrons221
9627397038isomersspecies with the same formula but different properties222
9627397039isotopesatoms of the same element with different numbers of neutrons223
9627397040ketoneorganic compound containing the carboxyl group bonded to two carbon atoms224
9627397041kinetic energy(1/2mv^2) energy due to the motion of an object; dependent on the mass of the object and the square of its velocity225
9627397042kinetic molecular theory (KMT)model that assumes that an ideal gas is composed of tiny particles (molecules) in constant motion226
9627397043lanthanide seriesgroup of 14 elements following lanthium in the periodic table in which the 4f orbitals are being filled227
9627397044lattice3D system of points designating the positions of the centers of the components of a solid228
9627397045lattice energyenergy change occuring when separated gaseous ions are packed together to form ionic solid229
9627397046law of conservation of energyenergy can be converted from one form to another but can be neither created nor destroyed230
9627397047law of conservation of massmass is neither created nor destroyed231
9627397048law of definite proportiongiven compound always contains exactly the same proportion of elements by mass232
9627397049law of mass actiongeneral description of the equilibrium condition233
9627397050law of multiple proportionswhen two elements form a series of compounds, the ratios of the masses of the second element that combine with one gram of the first element can always be reduced to small whole numbers234
9627397051le chatelier's principleif a change is imposed on a system at equilibrium, the position of the equilibrium will shift in a direction that tends to reduce the effect of that change235
9627397052lewis acidelectron pair acceptor236
9627397053lewis baseelectron pair donor237
9627397054lewis structurediagram of a molecule showing how the valence electrons are arranged among the atoms in the molecule238
9627397055ligandneutral molecule or ion having a lone pair of electrons that can be used to form a bond to a metal ion; a lewis base239
9627397056limiting reactant (limiting reagent)reactant that is completely consumed when a reaction is run to completion240
9627397057line spectrumspectrum showing only certain discrete wavelengths241
9627397058localized electron (LE) modelmodel which assumes that a molecule is composed of atoms that are bound together by sharing pairs of electrons using the atomic orbitals of the bound atoms242
9627397059london dispersion forcesforces, existing among noble gas atoms and nonpolar molecules, that involve an accidental dipole that induces a momentary dipole in a neighbor243
9627397060lone pairan electron pair that is localized on a given atom; an electron pair not involved in bonding244

Need Help?

We hope your visit has been a productive one. If you're having any problems, or would like to give some feedback, we'd love to hear from you.

For general help, questions, and suggestions, try our dedicated support forums.

If you need to contact the Course-Notes.Org web experience team, please use our contact form.

Need Notes?

While we strive to provide the most comprehensive notes for as many high school textbooks as possible, there are certainly going to be some that we miss. Drop us a note and let us know which textbooks you need. Be sure to include which edition of the textbook you are using! If we see enough demand, we'll do whatever we can to get those notes up on the site for you!