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Chapter 11 Liquids, Solids and Intermolecular Forces Flashcards

Chemistry by Nivaldo Tro

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341550537Liquids-have high densities in comparison to gases -have an indefinite shape and assume the shape of their container -have a definite volume; they are not easily compressed -moderate strength of intermolecular forces
341550538Solids-have high densities in comparison to gases -have a definte shape; they do not assume the shape of their container -may be crytalline or amorphous -strong intermolecular forces (IMF)
341550539Gas-has low density -has indefiniete shape -has indefinite volume -weak IMF
341550540Crystalline solid-the arrangement of the particles displays long-range order
341550541Amorphous solid-the arrangement of the particles has no long range order
341550542Intermolecular Forces (IMF)-originate from the interactions between charges, partial charges and temporary charges on molecules (or atoms or ions) -generally weaker than bonding forces
341550543Dispersion (London) forces-present in all molecules and atoms -the result of fluctuations in the electron distribution within molecules or atoms
341550544Dipole-Dipole Force-exist in all molecules that are polar
341550545Miscibilitythe ability to mix without separating into two phases
341550546Hydrogen bondingpolar molecules containing hydrogen atoms bonded directly to small electronegative atoms (most importantly N-O-F)
341550547Ion-dipole forceoccurs when an ionec compound is mixed with a polar compound and is especially important in aqueous solutions of ionic compounds -the stronges of the types of IMF -responsible for the ability of ionic sumbstances to form solutions with water.
341550548Surface tension-the energy required to increase the surface area by a unit amount of liquid -decreases with decreasing IMF
341550549Viscosity-the resistance of a liquid to flow -greater in substances with stronger IMF -it increases with increasing molar mass -decreases with increasing temperature
341550550Capillary Actionthe ability of a liquid to flow against gravity up a narrow tube
341550551Adhesive forcesthe attraction between molecules and the surface of the tube
341550552cohesive forcesthe attraction between molecules in a liquid
341550553Vaporizationthe phase change in which a substance changes from a liquid into a gas -endothermic
341550554condensationthe change from the gaseous to the liquid state of matter -exothermic
341550555volatileliquids that vaporize easily
341550556nonvolatileliquids that do not vaporize easily
341550557rate of vaporizationincreases with increasing temperature -increases with increasing surface area -increases with decreasing strength of IMF
341550558vapor pressurethe pressure of gas in dynamic equillibrium
341550559boiling pointthe temprerature at which its vapor pressure equals the external pressure
341550560critical temperaturerepresents the temperature above which the liquid cannot exist (regardless of pressure)
341550561supercritical fluidshas properties of both liquids and gases
341550562sublimationthe phase transition from solid to gas
341550563depositionthe phase transition from gas to solid
341550564melting pointthe molecules have enough thermal energy to overcome the IMF that hold them at their stationary points -solid to liquid
341550565freezing pointthe phase transition from liquid to solid
341550566phase diagrama map of the phase of a substance as a function of pressure and temperature.

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