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Chemistry Chapter 5: Modern Atomic Theory

Chemistry Chapter 5: Modern Atomic Theory

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a form of energy like heat or electricity
through space in waves
3.0×10¹⁰cm/s
the distance between two adjacent peaks in the wave; relates to the energy of light; designated by the Greek letter lamba: λ; what light energy is measured by
range of wavelengths; only a small part that is visible; colors are continuous
every light source has one;
its energy is inversely proportionate to its wavelength ε=hc/λ
constant proportionality known as "Planck's Constant"
the velocity of light in a vacuum
light that extends beyond violet; not visible but highly energetic; dangerous to living organisms
wavelengths longer than red
colors produced when wavelengths of light are separated; each element gives off its own one of these
proposed the model for sub-atomic arrangement
1) Electrons revolved around the nucleus in a stable, circular orbit (like planets around the sun) 2) Electrons appear in several different orbits (distances from the nucleus) a) electrons are quantized- they are at a definite, or discrete, distances from the nucleus b) each orbit is referred to as an energy level
each energy level is designated by their own one of these numbers; indicates the energy and orbital of an electron in an atom
the lowest energy level of an atom which electrons will occupy
a state in which an atom has a higher potential energy than it has in its ground state
highest wavelength possible, most powerful; it determines the color given off by the element
Electrons move very quickly because of their low mass; so one could not predict an electron's position with much certainty
the wave nature of the electron and the uncertainty of its location led to a complex mathematical approach to the electron in the hydrogen atom; this was used to predict the probability of an electron to be in a certain region of space (orbital)
the region of space where there is the significant probability of finding a particular electron; also called an "electron cloud"
spherical volume of probability; all energy levels have this orbital (n=1,2,3, etc) can hold a total of 2 electrons in 1 sub-shell
the second kind of orbital present starting with n=2,3,4, etc; has 2 lobes of high probability; can hold a total of 6 electrons in 3 sub-shells
orbitals of the same type (s, p, d, or f) in each shell (1,2,3,4,5,6, or 7) make up this; can hold 2 electrons per one of these
most have 4 lobes; and their destiny runs along the axes; can hold a total of 10 electrons in 5 sub-shells
their shapes are even more complex than s, p, or d orbitals; can hold a total of 14 electrons in 7 sub-shells
1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 5f 6s 6p 6d 6f 7s 7p 7d 7f
electrons occupy the available orbitals in the sub-shells of the lowest energy
the assignment of all the electrons into an atom in a specific shell and sub-shell (an electron's address)
states that no 2 electrons in the same orbital can have the same spin
representation of the orbitals in a sub-shell as boxes and its electrons as arrows
states that electrons occupy separate orbitals in the same sub-shell with parallel spins (in other words, electrons want their own space!)
the distance from the nucleus to the outer shell; decrease from left to right, increase from top to bottom; the more electrons an element has, the more it will want to hold them tighter and become smaller, the less they have the more empty space it has
the energy required to remove an electron from a gaseous atom to form a gaseous ion; since the outer electrons are less firmly attached, they are the 1st to go; it increases from left to right, and decreases from top to bottom

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