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Chemistry Final Outline Flashcards

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404459611Actual yieldthe amount of product that actually forms when the reaction is carried out in the laboratory
404459612Excess reagentthe reagent that is not completely used up in a reaction
404459613Limiting reagentthe reagent that determines the amount of product that can be formed by a reaction
404459614Mole ratioa conversion factor derived from the coefficients of a balanced chemical equation interpreted in terms of moles
404459615Percent yieldthe ratio of the actual yield to the theoretical yield expressed as a percent
404459616Stoichiometrya subject of chemistry about the calculation of quantities in chemical reactions
404459617Theoretical yieldthe maximum amount of product that could be formed from given amounts of reactants
404459618Phase diagrama graph that shows the relationships among the solid, liquid, and vapor states (or phases) of a substance in a sealed container gives the conditions of temperature and pressure at which a substance exists as solid, liquid, and gas (vapor) The conditions of pressure and temperature at which two phases exist in equilibrium are indicated on a phase diagram by a line separating the phases
404459619Compressibilitya measure of how much the volume of matter decreases under pressure
404459620Diffusionthe tendency of molecules to more toward areas of lower concentration until the concentration is uniform throughout
404459621Effusionduring it, a gas escapes through a tiny hole in its container
404459622Partial pressurethe contribution each gas in a mixture makes to the total pressure
404459623Aqueous solutionwater than contains dissolved substances
404459624Electrolytea compound that conducts an electric current when it is in an aqueous solution or in the molten state
404459625Hydratea compound that contains water of hydration
404459626Nonelectrolytea compound that does not conduct an electric current in either aqueous solution or the molten state Most molecular compounds are nonelectrolytes because they are not composed of ions
404459627Solutethe dissolving particles in a solution
404459628Solventthe dissolving medium in a solution
404459629Colligative propertya property that depends only upon the number of solute particles, and not upon their identity Three important _________________ of solutions are vapor-pressure lowering, boiling-point elevation, and freezing-point depression
404459630Miscibletwo liquids are miscible if they dissolved each other in all proportions. In such solutions, the liquid that is present in the larger amount is usually considered the solvent
404459631Immiscibleliquids that are insoluble in one another example is oil and water
404459632Molarity(m) the number of moles of solute dissolved in one liter of solution also known as molar concentration
404459633Molality(M) the number of moles of solute dissolved in 1 kilogram (1000 g) of solvent also known as molal concentration
404459634Mole fractionthe ratio of the moles of that solute to the total number of moles of solvent and solute
404459635Saturated solutioncontains the maximum amount of solute for a given quantity of solvent at a constant temperature and pressure
404459636Unsaturated solutiona solution that contains less solute than a saturated solution at a given temperature and pressure If additional solute is added to an unsaturated solution, the solute will dissolve until the solution is saturated
404459637Solubilitythe amount of a substance that dissolves in a given quantity of solvent at specified conditions of temperature and pressure to produce a saturated solution
404459638Endothermicone that absorbs heat from the surroundings in it, the system gains heat as the surroundings cool down
404459639Exothermicone that releases heat to its surroundings it in, the system loses heat as the surroundings heat up
404459640Heat capacitythe amount of heat needed to increase the temperature of an object exactly 1oC depends on the object's mass and its chemical composition The greater the mass of the object, the greater its heat capacity
404459641Specific heatthe amount of heat it takes to raise the temperature of 1 g of substance 1oC Heat affects the temperature of objects with a high specific heat much less than the temperature of those with a low specific heat
404459642Calorimetrythe precise measurement of the heat flow into or out of a system for chemical and physical processes in it, the heat released by the system is equal to the heat absorbed by its surroundings. Conversely, the heat absorbed by a system is equal to the heat released by its surroundings
404459643Heatrepresented by q energy that transfers from one object to another because of a temperature difference between them
404459644Systemthe part of the universe on which you focus your attention in studying energy changes
404459645Surroundingsinclude everything else in the universe
404459646Hess's law of heat summationstates that if you add two or more thermochemical equations to give a final equation, then you can also add the heats of reaction to give the final heat of reaction
404459647Enthalpy(H) the heat content of a system at constant pressure is the same as this property The heat released / absorbed by a reaction at constant pressure is the same as the change in enthalpy
404459648Law of conservation of energystates that in any chemical or physical process, energy is neither created nor destroyed If the energy of the system decreases during that process, the energy of the surroundings must increase by the same amount so that the total energy of the universe remains unchanged.
404459649Entropya measure of the disorder of a system
404459650Le Chatelier's principleif a stress is applied to a system in dynamic equilibrium, the system changes in a way that relieves the stress
404459651Spontaneous reactionoccurs naturally and favors the formation of products at the specified conditions produce substantial amounts of products at equilibrium and release free energy
404459652Nonspontaneous reactiona reaction that does not favor the formation of products at the specified conditions do not give substantial amounts of products at equilibrium
404459653Solubility product constantan equilibrium constant applied to the solubility of electrolytes it is equal to the product of the concentrations of the ions each raised to a power equal to the coefficient of the ion in the dissociation equation can be used to predict whether a precipitate will form when solutions are mixed
404459654Rate lawan expression for the rate of a reaction in terms of the concentration of reactants
404459655Reversible reactionone in which the conversion of reactants to products and the conversion of products to reactants occur simultaneously
404459656Gibbs free - energy changethe maximum amount of energy that can be doubled to another process to do useful work
404459657Free energyenergy that is available to do work
404459658First - order reactionin it, the reaction rate is directly proportional to the concentration of only one reactant
404459659Equilibrium constant(Keq) the ratio of product concentrations to reactant concentrations at equilibrium, with each concentration raised to a power equal to the number of moles of that substance in the balanced chemical equation
404459660Chemical equilibriumwhen the rates of the forward and reverse reactions are equal, the reaction has reached a state of balance
404459661Acid dissociation constantthe ratio of the concentration of the dissociated (or ionized) form of an acid to the concentration of the undissociated (nonionized) form The acid dissociation constant reflects the fraction of an acid in the ionized form Sometimes called ionization constants
404459662Amphotericsubstance that can act both as an acid and base
404459663Base dissociation constantthe ratio of the concentration of the conjugate acid times the concentration of the hydroxide ion to the concentration of the base
404459664Buffersa solution in which the pH remains relatively constant when small amounts of acid or base are added a solution of a weak acid and one of its salts, or a solution of a weak acid and one of its salts
404459665Buffer capacitythe amount of acid or base that can be added to a buffer solution before a significant change in pH occurs
404459666Conjugate acidthe particle formed when a base gains a hydrogen ion
404459667Conjugate basethe particle that remains when an acid has donated a hydrogen ion
404459668Titrationthe process of adding a known amount of solution of known concentration to determine the concentration of another solution
404459669Salt hydrolysisin it, the cations or anions of a dissociated salt remove hydrogen ions from or donate hydrogen ions to water
404459670Lewis acida substance that can accept a pair of electrons to form a covalent bond
404459671Lewis basea substance that can donate a pair of electrons to form a covalent bond
404459672End pointthe point of the titration at which the indicator changes color
404459673Equivalence pointwhen an acid and base are mixed, the point when the number of moles of hydrogen ions equals the number of moles of hydroxide ions
404459674Hydronium ion(H3O+) a water molecule that gains a hydrogen ion becomes this type of positively charged ion
404459675Oxidationcomplete or partial loss of electrons or gain of oxygen
404459676Reductioncomplete or partial gain of electrons or loss of oxygen
404459677Oxidation numbera positive or negative number assigned to an atom to indicate its degree of oxidation or reduction
404459678Half - reactionan equation showing just the oxidation or just the reduction that takes place in a redox reaction
404459679Anodethe electrode at which oxidation occurs Because electrons are produced at the anode, it is labeled the negative electrode
404459680Cathodethe electrode at which reduction occurs. Because electrons are consumed at the cathode, it is labeled the positive electrode
404459681Batterya group of cells connected together
404459682Cell potentialthe difference between the reduction potentials of the two half - cells
404459683Electrolytic cellan electrochemical cell used to cause a chemical change through the application of electrical energy uses electrical energy (direct current) to make a spontaneous redox reaction proceed to completion
404459684Voltaic cellelectrochemical cells used to convert chemical energy into electrical energy
404459685Salt - bridgeconnects the half - cells a tube containing a strong electrolyte
404459686Half - cellone part of a voltaic cell in which either oxidation or reduction occurs
404459687Isomerscompounds that have the same molecular formula but different molecular structures
404459688Saturated compoundorganic compounds that contain the maximum number of hydrogen atoms per carbon atom = the alkanes are an example
404459689Unsaturated compoundcompounds that contain double or triple carbon-carbon bonds
404459690Substituentan atom or group of atoms that can take the place of a hydrogen atom on a parent hydrocarbon molecule
404459691Alkaneshydrocarbon in which there are only single covalent bonds
404459692Alkeneshydrocarbons that contain one or more carbon-carbon double covalent bonds
404459693Alkyneshydrocarbons that contain one or more carbon-carbon triple covalent bonds
404459694Cycloalkanes...
404459695Ketonean organic compound in which the carbon of the carbonyl group is joined to two other carbons The general formula = RCOR.
404459696Hydroxyl groupthe - OH functional group in alcohols
404459697Functional groupspecific arrangement of atoms in an organic compound that is capable of characteristic chemical reactions
404459698Carboxylic acida compound with a carboxyl group The general formula for a carboxylic acid is RCOOH
404459699Carboxyl groupconsists of a carbonyl group attached to a hydroxyl group
404459700Carbonyl groupa functional group with the general structure C = O
404459701Aldehydean organic compound in which the carbon of the carbonyl group is always joined to at least one hydrogen The general formula = RCHO
404459702Alpha particlean emitted particle that contains two protons and two neutrons and has a double positive charge
404459703Beta particlean electron resulting from the breaking apart of a neutron in an atom
404459704Fissionthe splitting of a nucleus into smaller fragments
404459705Fusionit occurs when nuclei combine to produce a nucleus of greater mass
404459706Gamma raya high - energy photon emitted by a radioisotope
404459707Half - lifethe time required for one - half of the nuclei of a radioisotope sample to decay to products
404459708Positrona particle with the mass of an electron but a positive charge
404459709Transmutationthe conversion of an atom of one element to an atom of another element
404459710Radioactivitythe process by which materials give off rays

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