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Important Organic II Reactions Flashcards

This set contains a plethora of important reactions covered in Organic Chemistry II as listed in chapters 15 - 24 of "Organic Chemistry" by David Klein.

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1563208156Preparation of Dienes from Allylic Halides Synthesis: 1) t-BuOK0
1563208157Preparation of Dienes from Dihalides Synthesis: 1) t-BuOK1
1563208158Diene Electrophilic Addition with HBr Synthesis: 1) HBr2
1563208159Diene Electrophilic Addition with Br2 Synthesis: 1) Br23
1563208160Diels-Alder Reactions (1)4
1563208161Diels-Alder Retro Reactions (1)5
1563208162Diels-Alder Reactions (2)6
1563208163Diels-Alder Reactions (3)7
1563208164Diels-Alder Reactions (4)8
1563208165Diels-Alder Reactions (5)9
1563208166Electrocyclic Reactions (1)10
1563208167Electrocyclic Reactions (2)11
1563208168Electrocyclic Reactions (3) Synthesis: 1) Heat12
1563208169Electrocyclic Reactions (4) Synthesis: 1) hv13
1563208170Electrocyclic Reactions (5) Synthesis: 1) hv14
1563208172Electrocyclic Reactions (6) Synthesis: 1) Heat15
1563208173Sigmatropic Rearrangement (Cope) Synthesis: 1) Heat16
1563208174Sigmatropic Rearrangement (Claisen) Synthesis: 1) Heat17
1563679689Benzylic Position Oxidation Synthesis: 1) Na2Cr2O7, H2SO4, H2O 1) KMnO4, H2O, Heat 2) H3O+18
1563679690Benzylic Position Free-Radical Bromination Synthesis: 1) NBS, Heat19
1563679691Benzylic Position Elimination (E1) Synthesis: 1) Concentrated H2SO420
1563679692Benzylic Position Elimination (E2) Synthesis: 1) NaOEt21
1563679693Benzylic Position Substitution (SN1) Synthesis: 1) H2O22
1563679694Benzylic Position Substitution (SN2) Synthesis: 1) NaOH23
1563679695Benzylic Catalytic Hydrogenation Synthesis: 1) Ni, 100 atm, 150° C24
1563679696Birch Reduction (1,2) Synthesis: 1) Na, CH3OH, NH325
1563679697Birch Reduction (2,3) Synthesis: 1) Na, CH3OH, NH326
1563216499Electrophilic Aromatic Substitutions (Br) Synthesis: 1) Br2, AlBR327
1563216500Electrophilic Aromatic Substitutions (Cl) Synthesis: 1) Cl2, AlCl328
1563216501Electrophilic Aromatic Substitutions (NO2) Synthesis: 1) HNO3, H2SO429
1563216502Electrophilic Aromatic Substitutions (SO3H) Synthesis: 1) Fuming H2SO430
1563216503Removing Electrophilic Aromatic Substitution (SO3H) Synthesis: 1) Dilute H2SO431
1563216504Electrophilic Aromatic Substitutions (CH3) Synthesis: 1) CH3Cl, AlCl332
1563216505Electrophilic Aromatic Substitutions (COCH2CH3) Synthesis: 1) ClCOCH2CH3, AlCl333
1563216506Electrophilic Aromatic Substitutions (NH2) Synthesis: 1) Fe or Zn, HCl34
1563216507Electrophilic Aromatic Substitutions (CBr3) Synthesis: 1) Xs NBS35
1563216508Electrophilic Aromatic Substitutions (COOH) Synthesis: 1) KMnO4, NaOH, Heat 2) H3O+36
1563216509Electrophilic Aromatic Substitutions (CH2CH2CH3) Synthesis: 1) Zn(Hg), HCl, Heat37
1563216510Nucleophilic Aromatic Substitutions Synthesis: 1) NaOH, 70° C 2) H3O+38
1563216511Aromatic Elimination-Addition (OH) Synthesis: 1) NaOH, 350° C 2) H3O+39
1563216512Aromatic Elimination-Addition (NH2) Synthesis: 1) NaNH2, NH3 (l) 2) H3O+40
1563220782Hydrate Formation Synthesis: 1) [H+], H2O41
1563220783Acetal Formation Synthesis: 1) [H+], ROH, -H2O42
1563220784Cyclic Acetal Formation Synthesis: 1) [H+], HOCH2CH2OH, -H2O43
1563220785Cyclic Thioacetal Formation Synthesis: 1) [H+], HSCH2CH2SH, -H2O44
1563220786Imine Formation Synthesis: 1) [H+], RNH2, -H2O45
1563220787Enamine Formation Synthesis: 1) [H+], R2NH, -H2O46
1563220788Oxime Formation Synthesis: 1) [H+], NH2OH, -H2O47
1563220789Hydrazone Formation Synthesis: 1) [H+], NH2NH2, -H2O48
1563220790Reduction of a Ketone Synthesis: 1) LAH 2) H2O49
1563220791Grignard Reaction Synthesis: 1) RMgBr 2) H2O50
1563220792Cyanohydrin Formation Synthesis: 1) HCN, KCN51
1563220793Wittig Reaction Synthesis: 1) H2C=PPh352
1563220794Baeyer-Villiger Oxidation Synthesis: 1) RCO3H53
1563220795Desulfurization Synthesis: 1) Raney Ni54
1563220796Wolf-Kishner Reduction Synthesis: 1) NaOH, H2O, Heat55

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