AP Notes, Outlines, Study Guides, Vocabulary, Practice Exams and more!

SKILLS: Equilibrium and Rates etc. Flashcards

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397048750What are the factors that affect the rate of a chemical reaction?Temperature, pressure, concentration, use of a catalyst, state of subdivision or particle size, stirring and nature of reactants.
397048751What is a transition state or activated complex?The transition state is the point in the reaction where new bonds are forming and the original bonds are breaking. It is the highest PE state for the reaction.
397048752Does a change in mass alone affect the rate of a chemical reaction?No.
397048753What is Ea?Ea (activation energy) is the minimum energy required for a successfully reactive collision.
397048754What is an exothermic reaction?A reaction that converts PE into KE. -Temp. increases. -There is a gain in electron(s). -The energy term in the equation is on the right of the arrow. -The change in H is -ve. -Particles are closer. -Bonds are formed.
397048755What is enthalpy (H)?H is stored energy or PE.
397048756What is an endothermic reaction?A reaction that converts KE into PE. -Temp. decreases. -Electron(s) are given away -The energy term in the equation is on the left of the arrow. -The change in H is +ve. -Particles are further apart -Bonds are broken
397048757What does the term 'heat of reaction' mean?The heat of reaction is the change in PE during a chemical reaction. It has the symbol, (delta)H.
397048758The Haber Process is used to manufacture ammonia: N2(g) + 3H2(g) <-> 2NH3(g) What reaction conditions should be used to maximise yield?The forward reaction is exothermic and hence will be favoured by lower temperatures. High pressure favours the reaction as it produces the fewest moles of gas in the system. The removal of NH3 as it is forward, as this will favour the forward reaction.
397048759A saturated solution of strontium hydroxide containing some undissolved solid was prepared. Would this solution be in a state of equilibrium?Yes. This is because the two opposing processes are occurring at the same rate. i.e. Some of the undissolved solid particles will be dissolving and some of the undissolved particles will become solid.

Chemical Equilibrium and Rates of Reactions Flashcards

Factors that affect reaction rate
Conditions at equilibrium
Shifts in equilibrium

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817904529True or False: Reaction rate is proportional to the number of effective collisions.True! Reactions happen due to collisions
817904530List 4 ways to increase collisions and thus increase reaction rate.1) Increase temperature (for solids) - this increases energy= increases movement = increases collisions 2) Increase surface area by crushing the reactants into smaller pieces - This increases the # of particles having collisions 3) Add a catalyst - this lowers the activation energy so reactants don't have to gain as much energy to react 4) Increase the concentration of the reactants = increases the # of particles colliding
817904531In a potential energy diagram for a reaction, the presence of a catalyst will be shown with what?It will be shown with a dashed line that is below the original activation energy curve.
817904532What does chemical equilibrium mean?Equal rates of forward (reactants to products) and reverse (products to reactants) reactions. Does NOT mean equal amounts of the reactant and product just equal rates of transfer!
817904533In an equilibrium expression, the _____ go on top in brackets.Products
817904534A K (equilibrium constant) greater than 1 tells you that the reaction:proceeds mostly to completeion (to products)
817904535When a reaction is at equilibrium and the pressure is increased, how will it react?It will shift to the side with less mess - side with less stuff on it!
817904536A reaction is at equilibrium. One of the reactants is increased. What happens?Shift to the product side to use up extra reactant.
817904537A reaction is at equilibrium. One of the reactants is constantly removed from the reaction. What happens?Shift to the reactant side to replace the removed reactant.

C2 - Gases, Kinetics, and Chemical Equilibrium Flashcards

2.1 - Gases
2.2 - Kinetic Molecular Theory
2.3 - Real Gases
2.4 - Chemical Kinetics
2.5 - Collision Theory
2.6 - Equations for REaction Rates
2.7 - Determining the Rate Law by Experiment
2.8 - Recognizing Reaction Orders
2.9 - Rates of Reversible Reactions
2.10- Catalysis
2.11 - Effects of Solvent on Rate
2.12 - Equilibrium
2.13 - The Partial Pressure Equilibrium Constant
2.14 - The Reaction Quotient
2.15 - Le Chatelier's Principle

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775921170What is the standard temperature and pressure (STP) ?1. 0 degrees C 2. 1 atm
775921171In the Kinetic Molecular Theory, we have the model of an ideal gas. What are the 4 characteristics of an ideal gas?1. ideal gases have 0 volume 2. Gas molecules exert no forces other than repulsive forces due to collisions 3. Elastic collisions only made 4. EK of gas molecules proportional to T
775921172What is the Ideal gas Law equation?PV = nRT - P: in atm - V: in L - n: number of moles of gas - T: in K - R: 0.08206 L atm/ Kmol or 8.314J/Kmol
775921173At STP, one mole of any gas behaving ideally will occupy how many L?22.4 L standard molar volume
775921174What is partial pressure and its equation?Partial pressure of a gas is the total pressure of the gaseous mixture times the mole fraction of the particular gas. Pa = XaPtotal - Xa = mole fraction
775921175What is Dalton's law?States that the total pressure exerted by a gaseous mixture is the sum of the partial pressures of each of its gases. Ptotal = P1 + P2 + P3...
775921176What is the equation for the average translational kinetic energy of a gas?KEavg = 3/2 RT - This is for a mole of gas molecules and not the energy of every or any of the molecules
775921177What is Graham's law? What is the equation for it?Graham's law is the relationship that gives the ratio of the rms velocities of two gases in a homogeneous mixture. v1/v2 = sqrt(m2/m1) - Avg speed of molecules are inversely proportional to the sqrt of the mass.
775921178What is the difference between effusion and diffusion?1. Effusion is the spreading of a gas from high pressure to low pressure through a pinhole. - Molecules with higher rms velocity will experience more collisions with container walls, the rate the gas will find the pinhole will be greater 2. Diffusion is the spreading of one gas into another gas or into empty space.
775921179What is the equation for effusion rate/diffusion rate as predicted by Graham?- Same as Graham's equation: effusion rate 1/ effusion rate 2 = sqrt (M2/M1)
775921180What are 2 ways real gases deviate from ideal behavior?- When gases are pushed close together, they exhibit nonideal behavior. 1. V real > V ideal molecule because real gases do have V, their V must be added to the ideal V. 2. Real gases do exhibit forces on each other and are attractive when molecules are far apart, pulling them inward so they strike the container with less force. Preal < Pideal
775921181For 1 mole of ideal gas, how does volume cause ideal behavior to deviate?Volume causes PV/RT to deviate positively from ideal behavior because V increases. Real gases occupy volumes greater than predicted, especially as Pressure increases, gas V takes a larger fraction of total space.
775921182For 1 mole of ideal gas, how does intermolecular forces cause deviations of ideal behavior?Intermolecular forces cause PV/RT to deviate negatively from ideal behavior because the pressure/force of molecule against the wall of the container is less than 1.
776330703What is the difference between Kinetics and themodynamics?1. Kinetics deals with the rate of a reaction as it moves toward equilibrium and tells us how fast equilibrium is achieved. 2. Thermodynamics deals with the balance of reactants and products after they have achieved equilibirum - tells us what equilibrium looks like. -Lower Ea forms kinetic products but thermodynamically favored products have lower energy/more stability.
776330704What are the 2 requirements for a given collision to create new molecules in a reaction?1. The relative kinetic energies of colliding molecules reach a threshold energy called activation energy 2. Proper spatial orientation
776330705What does the rate of a reaction tell you? What are the units?How quickly the concentration of a reactant or product is changing. Molarity (mol/Ls)
776330706What are intermediates?Species that are products of one reaction and reactants of a later reaction in a reaction chain. They are often unstable and react as quickly as they're formed.
776330707What is the rate law reaction for only the forward reaction?rate = k[A]m[B]n
776330708What is meant by 0 order?When there's no reverse reaction, 0 order reactions have a constant rate that is independent of the concentration of the reactants.
776330709What is 1st order?rate is directly proportional to the concentration of the reactant. Doubling the concentration increases the rate by a factor of 2
776330710What is 2nd order?the rate is to the square of the concentration of the reactant. Doubling the concentration increases the rate by a factor of 4
776330711What does rate constant "k" tell you? What are the 2 things it's dependent on?"k" is called the rate constant. It is independent of the other quantities in the equation. It is dependent on: 1. the nature of the reaction "fast" reactions typically have large rate constants if k is small, the reaction is slow at ordinary concentration 2. the temperature ordinarily, k increases with temperature
776330712What is the rate determining step?The rate of the slowest step determines the rate of the overall reaction. Steps after the rate determining step make no contribution to the rate law but steps before do, so we have to include the intermediate in the determination of the rate law.
776330713What is a catalyst?A substance that increases the rate of a reaction in both directions without being consumed or altered. When the Ea is lowered, more collisions have sufficient relative kinetic energy to create a reaction.
776330714What are 2 phases of catalysts? How can we increase reaction rates using either catalyst?1. Heterogeneous catalyst - in a different phase than reactants and products. (i.e. solids) that allow reactants to adsorb to its surface. Reaction rates can be increased by increasing surface area. 2. Homogeneous catalyst - same phase as reactants/products (usually gas/liquid). Increasing concentration of the catalyst increases rate of reaction.
776330715What is the effect of solvent on reaction rate of a liquidRate constant in a liquid is a function of the solvent as well as temperature. Solvents surround the liquid like a cage and the liquid must escape before reacting with another reactant. Thus, collisions in a liquid occur at about the same rate as in a gas.
776596610What is the rate at equilibrium?0 b/c forward rate = reverse rate
776596611In what type of reaction CAN you use the stoichiometric coefficients as the reaction orders in the rate law equation?Elementary reactions (single step) and not multistep because you can have a reactant that appears in the overall reaction but does not appear in the slowest step of that mechanism, then that reactant is zero order and will not appear in the rate law.
776596612What is the law of mass action? Write the equation for it.Kc=[C]c[D]d/[A]a[B]b States that the rate of an elementary reaction and non-elementary is proportional to the concentrations of the participating molecules during an equilibrium reaction. If it's an equilibrium rxn, then the above ratio is a constant. - K has no dimensions
776596613What is the difference between rate constant k and equilibrium constant K?Rate constant tells you the speed of the reaction. Equilibrium constant tells you when the reaction is at equilibrium.
776596614Equilibrium constant depends on?Temperature only! Not pressure! If the forward rxn is exothermic, increasing temperature decreases K (by being less product favored). If the fwd reaction is endothermic, increasing T increases K.
776596615Why are pure liquids or solids given a value of 1 for the equilibrium?This is because they do not effect the reactant amount at equilibrium in the reaction, so they are disregarded and kept at 1.
776596616The equilibrium constant describes only equilibrium conditions. What is used when the reaction isn't at equilibrium? What is the equation?Reaction quotient Q is used to predict the direction a reaction will proceed to equilibrium. Q = products ^coefficients/ reactants ^coefficients
776596617If K=Q?Reaction is at equilibrium
776596618If Q>K?The ratio of products is greater than reactants so the reverse reaction is favored.
776596619If QThe ratio of the products to the reactants is lower - there are more reactants than products. The forward reaction is favored.
776596620What does Le Chatelier's principle state?When a system at equilibrium is stressed, it'll shift in a direction that will reduce that stress.
776596621What are the 3 stresses in Le Chatelier's principle?1. Addition/Removal of a product or reactant 2. Changing the pressure of the system 3. Heating or cooling the system
776596622Which direction is the shift predicted by LC's principle if the pressure is increased? If pressure is decreased?1. It will shift to the side with fewer moles. 2. It will shift to the side with more moles
776596623Why does adding a nonreactive gas not shift the equilibrium even though pressure increases?Adding an inert gas does not change the partial pressures and total pressure increase doesn't have an effect on the equilibrium constant. Only partial pressures have an effect
776596624Why does LC's Principle not predict shift during solvation reactions?Solubility of salts increase when temperature increases, even when reaction is exothermic. Equilibrium will shift to the right when it's predicted not to.

LC Chemistry Equilibrium Flashcards

Flash cards suitable for studying Chemical Equilibrium in the Leaving Certificate Chemistry course

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280108363Chemical EquilibriumA state of dynamic balance where the rate of the forward reaction equals the rate of the reverse reaction
280108364DynamicThe reaction has not stopped
280121348Le Chatelier's PrincipleReactions at equilibrium oppose applied stresses
280121349The Haber ProcessIndustrial production of Ammonia. Ideal conditions for production are high pressure and low temperature. Industrially a temperature of 500°Celcius and a pressure of 200 atmospheres is applied. An iron catalyst is used.
280121350The Contact ProcessIndustrial production of Sulphur Trioxide. Ideal conditions for production are high pressure and low temperature. Industrially a temperature of 450°Celcius and a pressure of just above atmospheric pressure is applied. Vanadium Pentoxide is used as a catalyst.
280121351Equilibrium Constant (Kc)

Reaction Rates and Equilibrium Flashcards

rates of reaction; the progress of chemical reactions; reversible reactions and equilibrium; solubility equilibrium; free energy and entropy

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771668497ratea measure of how much something changes within a specified amount of time
771668498average speed=Distance (m)/ Time (s)formula for average speed
771668499change; reactant; product; unit timeIn chemistry, the rate of a chemical reaction, or the reaction rate is usually expressed as the ____________ in the amount of _____________ or _____________ per _________ _________
771668500molesWhat is the amount of reactant usually expressed in?
771668501collision theoryatoms, ions, and molecules can react to form products when they collide if the particles have enough kinetic energy
771668502activation energythe minimum energy that colliding particles must have in order to react
771668503activated complexan unstable arrangement of atoms that forms for a moment at the peak of the activation energy barrier
771668504temperature, concentration, particle size, catalystWhat are four factors that can affect the rate of a chemical reaction?
771668505speeds up; particles move fasterRaising the temperature does what to a reaction? Why?
771668506trueIncreased concentration speeds up the reaction
771668507smaller, greaterThe ________ the particle size, the _______ the surface area is for a given mass of particles
771668508dissolve themAnother way to increase surface area of solids
771668509catalystsubstance that increases the rate of a reaction without being used us during the reaction
771668510lower energy pathCatalysts permit reactions to proceed along a _______ ________ _________
771668511inhibitora substance that interferes with the action of a catalyst
771668512ΔA/Δt=k(A)rate law equation
771668513rate lawexpression for the rate of a reaction in terms of the concentration of reactants
771668514specific rate constanta proportionality constant relating the concentration of reactants to the rate of the reaction
771668515quickly, slowlyThe value of the specific rate constant, k, in a rate law is large if the products form ___________; the value is small if the products form __________
771668516order of a reactionthe power to which the concentration of a reactant must be raised to match the experimental data on concentration and rate
771668517first-order reactionthe rate is directly proportional to the concentration of only one reactant
771668518elementary reactiona reaction in which reactants are converted to products in a single step
771668519TrueMost chemical reactions consist of two or more elementary reactions
771668520reaction mechanismthe series of elementary reactions or steps that take place during the course of a complex reaction
771668521intermediatea product of one step n a reaction mechanism and a reactant in the next step
771668522slowest stepThe _________ ________ will determine, or limit, the rate of the overall reaction
771668523reversible reactiona reaction in which the conversion of reactants to products and the conversion of products to reactants occur at the same time
771668524chemical equilibriumwhen the rates of the forward and reverse reactions are equal the reaction has reached a state of balance
771668525continue, rates are equal, net changeAt chemical equilibrium, both the forward and reverse reactions _________, but because their ___________ ___ ________, no _____ _________ occurs in the concentrations of the reaction components
771668526equilibrium positionthe relative concentrations of the reactants and products at equilibrium mark
771668527Le Châtelier's principleif a stress is applied to a system in dynamic equilibrium, the system changes in a way that relieves the stress
771668528Fritz HaberCame up with a way to make NH₃ using Le Châtelier's principle
771668529unequalA shift because of the pressure will occur only if there are an ________ number of moles of gas on each side of the equation
771668530equilibrium constantthe ratio of product concentrations to reactant concentration at equilibrium
771668531molesEach concentration is raised to a power equal to the number of ______ of that substance in the balanced chemical equation
771668532product, reactantWhen K(equilibrium) has a large value the reaction mixture at equilibrium will consist mainly of _______________, when it is a small value it will consist of __________
771668533solubility product constantconstant equal to the product of the concentrations of the ions each raised to a power equal to the coefficient of the ion in the dissociation equation
771668534lowerThe smaller the value of the solubility product constant, the _____________ the solubility of the compound
771668535common ionan ion that is found in both ionic compounds in a solution
771668536common ion effectthe lowering of the solubility of an ionic compound as a result of the addition of a common ion
771668537free energyenergy available to do work
771668538spontaneous reactionoccurs naturally and favors the formation of products at the stated conditions
771668539products and free energyWhat do spontaneous reactions produce?
771668540nonspontaneous reactionchemical reaction that does not favor the formation of products at the stated conditions
771668541Entropya measure of the disorder of a system
771668542law of disorderstates that the natural tendency is for systems to move in the direction of increasing disorder or randomness
771668543ΔG=ΔH-tΔSGibbs equation; temperature must be in kelvin
771668544negative, positiveWhen the value of ΔG is ____________ a process is spontaneous, if it is __________ it is non spontaneous

Ch.15- Chemical Equilibrium Flashcards

The Concept of Equilibrium, The Equilibrium Constant, Understanding and Working with Equilibrium Constants, Heterogenous Equilibria, Calculating Equilibrium Constants, Applications of Equilibrium Constants, Le Chatelier's Principle

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331814727chemical equilibriumthe rate at which the products form from the reactants equals the rate at which the reactants for the products (opposing reactions proceeding at equal rates)
331814728Haber processthe catalyst system and conditions of temperature and pressure developed by Fritz Haber and coworkers for the formation of NH₃ (ammonia) from H₂ and N₂ Real- Life Application: The quantity of food required to feed the ever increasing human population far exceeds that provided by nitrogen- fixing plants. Therefore, human agriculture requires substantial amounts of ammonia- based fertilizers for croplands.
331814729la of mass actionthe relationship between the concentrations of the reactants and products present at equilibrium general equilibrium equation: aA +bB ↔ dD +eE where A, B, D, E are chemical species involved and a, b, d, and e are their coefficients
331814730equilibrium-constant expressionsee bk pg 614
331814731equilibrium constant (kc)the numerical value obtained when we substitute molar equilibrium concentrations into the equilibrium- constant expression
331814732homogenous equilibriaequilibria involve substances that are all in the sam phase (usually gas or liquid)
331814733heterogenous equilibriasubstances in equilibria are in different phases
331814734reaction quotient (Q)a number obtained by substituting reactant and product concentrations or partial pressures at any point during a reaction into an equilibria-constant expression
331814735Comparing Q and KThe possible situations: Q=K: the reaction quotient equals the equilibrium constant only if the system is at equilibrium Q>K: the concentration of products is too large and that of reactants too small. Substances on the right side of the chemical equation react to form substances on the left; the reaction proceeds from right to left to approach equilibrium Q
331814736Le Châtelier's principlea principle stating that when we disturb a system at chemical equilibrium, the relative concentrations of reactants and products shift so as to partially undo the effects of the disturbance

AP Biology: Chapter 6 Flashcards

Vocabulary words from the AP Edition of Campbell Biology, Chapter 6.

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239457993organellesmembrane-enclosed compartments0
239457994cell fractionationtakes cells apart and separates the major organelles and other sub-cellular structures from one another1
239457995cytosola jellylike substance where organelles and other components are found2
239457996eukaryotic cellcell in which most DNA is found in the nucleus3
239457997prokaryotic cellcell in which most DNA is found in a non-membrane-enclosed nucleoid4
239457998nucleoida non-membrane-enclosed region of the cell where prokaryotic DNA is found5
239457999cytoplasmthe interior of a prokaryotic cell6
239458000plasma membranea selective barrier that allows sufficient passage of oxygen, nutrients, and wastes to service the entire cell7
239458001nucleuschromosome-containing part of a eukaryotic cell8
239458002nuclear envelopeencloses the nucleus to separate its contents from the cytoplasm9
239458003nuclear laminaa netlike array of protein filaments that maintains the shape of the nucleus by mechanically supporting the nuclear envelope, lines the nuclear side of the nuclear envelope10
239458004chromosomesstructures that carry the genetic information11
239458005chromatinmaterial that makes up chromosomes, a complex of proteins and DNA12
239458006nucleoluslocated in the nucleus, makes, synthesizes, and partially assembles ribosomes13
239458007ribosomesmade of ribosomal RNA and protein, synthesize proteins14
239458008endomembrane systemcollection of membranes related through direct physical contact or by the transfer of membranous vesicles15
239458009endoplasmic reticulumaccounts for more than half of total membrane in many eukaryotic cells, continuous with the nuclear envelope16
239458010smooth ERportion of the endoplasmic reticulum free of ribosomes, synthesize lipids, common in liver cells17
239458011rough ERportion of the endoplasmic reticulum studded with ribosomes, produce membrane and secretory proteins18
239458012glycoproteinsproteins with covalently-bonded carbohydrates19
239458013transport vesiclesvesicles in transit from one part of the cell to another20
239458014Golgi apparatusstack of membranes that modifies, sorts, and packages proteins from the endoplasmic reticulum21
239458015lysosomemembranous sac of hydrolytic enzymes, which it uses to digest macromolecules22
239458016phagocytosisthe lysosome digests food23
239458017autophagythe lysosomes break down damaged organelles24
239458018food vacuolesformed by phagocytosis, pinches off from plasma membrane and encloses a food particle25
239458019contractile vacuolespump excess water out of the cell to maintain a suitable concentration of ions and molecules in the cell26
239458020central vacuolecommon in mature plant cells, diverse roles in reproduction, growth, and development27
239458021mitochondriachemically convert energy through cellular respiration28
239458022chloroplastsconvert light energy to chemical energy (photosynthesis)29
239458023cristaeinfoldings in the inner membrane of the mitochondria30
239458024mitochondrial matrixcompartment of the mitochondrion, enclosed by the inner membrane, contains enzymes and substrates for the citric acid cycle31
239458025plastidsclosely related plant organelles32
239458026thylakoidsmembraneous system in the chloroplast, flattened and interconnected sacs33
239458027granumstacks of thylakoids34
239458028stromafluid outside the thylakoids, contains chloroplast DNA, ribosomes, and enzymes35
239458029cytoskeletona network of fibers bracing the cytoplasm36
239458030motor proteinsspecialized proteins, modify shape and move cells or structures within cells, required to interact with cytoskeleton for cell motility37
239458031microtubuleshollow rods of protein, support the cell and moves organelles within the cell38
239458032centrosomea region located near the nucleus where microtubules grow from39
239458033centriolestwo exist in the centrosome, each composed of nine sets of triplet microtubules arranged in the ring40
239458034flagellaa long tail-like feature found in one-celled organisms to aid in movement, utilizes a snakelike motion41
239895867ciliaa short hair-like structure made of microtubules that enable movement of cells or movement of materials outside a cell, utilizes a back-and-forth motion42
239895868basal bodyanchors cilium or flagellum in the cell43
239895869dyneinsmotor proteins responsible for bending movements of cilium and flagellum, composed of several polypeptides44
239895870microfilamentsseem present in all eukaryotic cells, located in the cytoplasm, acts (sometimes with myosin) to cause cell contraction45
239895871actina globular protein that makes up microfilaments46
239895872cortexthe outer cytoplasmic layer of a cell47
239895873pseudopodiacellular extensions that enable a cell to crawl along a surface48
239895874cytoplasmic streamingthe circular flow of cytoplasm within cells49
239895875intermediate filamentsdiverse class of cytoskeletal elements that bear tension like microfilaments50
239895876cell wallextracellular structure specific to plant cells, protects the cell, maintains its shape, and prevents excessive water uptake51
239895877primary cell walla relatively thin and flexible layer in plant cells, first secreted by a young cell52
239895878middle lamellaa thin layer between primary walls of adjacent cells that glues them together with pectin53
239895879secondary cell walla strong and durable matrix in plant cells, often deposited in several laminated layers for cell protection and support54
239895880extracellular matrixanimal tissue cells are embedded, consists of protein and polysaccharides55
239895881collagenmost common glycoprotein in the ECM, forms strong fibers outside the cells56
239895882proteoglycansconsists of a small core protein with many carbohydrate chains covalently attached,57
239895883fibronectinattach the ECM to integrins embedded in the plasma membrane58
239895884integrinsmembrane proteins with two subunits, bind to the ECM on one side and to associated proteins attached to microfilaments on the other59
239895885plasmodesmatachannels that perforate cell walls, allow for connections between cells in plants60
239895886tight junctionsintercellular junction in animal tissues where plasma membranes of neighboring cells are very tightly pressed against each other, bound by specific proteins61
239895887desmosomesintercellular junction in animal tissues that function like rivets, fastening cells together into strong sheets62
239895888gap junctionsintercellular junction in animal tissues that provide cytoplasmic channels from one cell to an adjacent cell, similar to plasmodesmata in plants63

Health in the 21st Century Flashcards

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898746854healthmore than merely the absence of illness or injury, a state of well-being that encompasses physical, social, psychological, spiritual, intellectual, environmental, and occupational dimensions
898746855wellnessthe process of actively making choices to achieve optimal health
898746856life expectancythe average number of years a person can expect to live
898746857Healthy People initiativea federal initiative to facilitate broad, positive health changes in large segments of the U.S. population every 10 years
898746858health disparitiesdifferences in quality of health among various segments of the population
898746859Healthy Campusan offshoot of the Healthy People initiative, specifically geared toward college students
901023875sexthe biological and physiological features that differentiate a male from a female
901023877health literacythe ability to evaluate and understand health information and to make informed choices for your health care
901023879behavior changea change in an action or habit that affects health
901023880predisposing factora physical, mental, emotional, or surrounding influence that shapes behavior
901023881enabling factora skill, asset, or capacity that shapes behavior
901023882reinforcing factoran encouragement or a reward that promotes behavior change
901023883transtheoretical model of behavior changea model of behavior change that focuses on decision-making steps and abilities. Also called the Stages of Change model
901023884health belief modela model of behavior change emphasizing personal beliefs in the process of creating effective change
901023885locus of controla person's belief about where the center of power lies in his or her life; can be external or internal
904089822modelinga behavior change technique based on watching and learning from others
904089823shapinga behavior change technique based on breaking large tasks into more manageable parts
904089824reinforcementa motivational behavior change technique that rewards steps toward positive change
904089825changing self-talkshifting one's internal dialogue in a more positive, empowering direction

Stamp Act Flashcards

The Stamp Act was a tax on many paper goods. The British felt that they deserved the money for protection and war expenses.

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228340338Stamp ActThe ________ was a tax on many paper goods. The British felt that they deserved the money for protection and war expenses.
228340339BoycottRefusal to buy goods.
228340340Tariffa tax on imported goods.
228340341Townsehend ActsThe _________ imposed tariffs on imported goods.
228340342First Continental CongressA 1774 meeting at which representatives from the colonies voted to stop trading with Britain and to start training colonists to fight.
228340343Militia_________ are volunteer soldiers that the British trained.
228340344MinutmenSome militias were called _________(soldiers ready to fight for the colonies in a minut's notice.)
228340345Patriots__________ fought against the KING.
228340346Loyalists___________ agreed with the KING.
228340347Intolerble Acts__________ were laws imposed by Britian that were punishments for the Boston Tea Party.

Macroeconomics terms-McGraw Hill Flashcards

An Introduction to Macroeconomics;
Measuring Domestic Output and National Income; Economic Growth;
Business Cycles, Unemployment, and Inflation;
Basic Macroeconomics Relationships

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346175107business cycleRecurring increases and decreases (fluctuations) in the level of in economic activity over periods of years; consists of peak, recession, trough, and expansion phases. (such as employment and production)
346175109economicsthe study of how society manages its scarce resources
346175111efficiencythe property of society getting the most it can from its scarce resources
346175113equalitythe property of distributing economic prosperity uniformly among the members of society
346175115externalitythe impact of one person's actions on the well-being of a bystander
346175117incentivesomething that induces a person to act
346175120inflationA rise in the general level of prices in an economy.
346175122marginal changessmall incremental adjustments to a plan of action
346175124market economyan economy that allocates resources through the decentralized decisions of many firms and households as they interact in markets for goods and services
346175126market failurea situation in which a market left on its own fails to allocate resources efficiently
346175128market powerthe ability of a single economic actor (or small group of actors) to have a substantial influence on market prices
346175129opportunity costwhatever must be given up to obtain some item
346175131productivitythe quantity of goods and services produced from each unit of labor input
346175133property rightsthe ability of an individual to own and exercise control over scarce resources
346175135rational peoplepeople who systematically and purposefully do the best they can to achieve their objectives
346175136scarcitythe limited nature of society's resources
346175137circular-flow diagrama visual model of the economy that shows how dollars flow through markets among households and firms
346175138macroeconomicsthe study of economy-wide phenomena, including inflation, unemployment, and economic growth
346175139microeconomicsthe study of how households and firms make decisions and how they interact in markets
346175140normative statementsclaims that attempt to prescribe how the world should be
346175141positive statementsclaims that attempt to describe the world as it is
346175142production possibilities frontiera graph that shows the combinations of output that the economy can possibly produce given the available factors of production and the available production technology
346175143absolute advantagethe ability to produce a good using fewer inputs than another producer
346175144comparative advantagethe ability to produce a good at a lower opportunity cost than another producer
346175145exportsgoods produced domestically and sold abroad
346175146importsgoods produced abroad and sold domestically
346175147opportunity costwhatever must be given up to obtain some item
346175148competitive marketa market in which there are many buyers and many sellers so that each has a negligible impact on the market price
346175149complementstwo goods for which an increase in the price of one leads to a decrease in the demand for the other
346175150demand curvea graph of the relationship between the price of a good and the quantity demanded
346175151demand schedulea table that shows the relationship between the price of a good and the quantity demanded
346175152equilibriuma situation in which the market price has reached the level at which quantity supplied equals quantity demanded
346175153equilibrium pricethe price that balances quantity supplied and quantity demanded
346175154equilibrium quantitythe quantity supplied and the quantity demanded at the equilibrium price
346175155inferior gooda good for which, other things equal, an increase in income leads to a decrease in demand
346175156law of demandthe claim that, other things equal, the quantity demanded of a good falls when the price of the good rises
346175157law of supplythe claim that, other things equal, the quantity supplied of a good rises when the price of the good rises
346175158law of supply and demandthe claim that the price of any good adjusts to bring the quantity supplied and the quantity demanded for that good into balance
346175159marketa group of buyers and sellers of a particular good or service
346175160normal gooda good for which, other things equal, an increase in income leads to an increase in demand
346175161quantity demandedthe amount of a good that buyers are willing and able to purchase
346175162quantity suppliedthe amount of a good that sellers are willing and able to sell
346175163shortagea situation in which quantity demanded is greater than quantity supplied
346175164substitutestwo goods for which an increase in the price of one leads to an increase in the demand for the other
346175165supply curvea graph of the relationship between the price of a good and the quantity supplied
346175166supply schedulea table that shows the relationship between the price of a good and the quantity supplied
346175167surplusa situation in which quantity supplied is greater than quantity demanded
346175168consumptionspending by households on goods and services, with the exception of purchases of new housing
346175169GDP deflatora measure of the price level calculated as the ratio of nominal GDP to real GDP times 100
346175170government purchases(G) Expenditures by government for goods and services tat government consumes in providing public goods and services that government consumes in providing public goods and for public (social) capital that has a long lifetime; the expenditures of all governments in the economy for those final goods and services. (spending on goods and services by local, state, and federal governments).
346175171gross domestic product (GDP)The total market value of all final goods and services produced annually, within the boundaries within a country (ex.United States), whether by U.S.-or foreign-supplied resources.
346175172investmentspending on capital equipment, inventories, and structures, including household purchases of new housing
346175173macroeconomicsthe study of economy-wide phenomena, including inflation, unemployment, and economic growth
346175174microeconomicsthe study of how households and firms make decisions and how they interact in markets
346175175net exportsspending on domestically produced goods by foreigners (exports) minus spending on foreign goods by domestic residents (imports)
346175176nominal GDPthe production of goods and services valued at current prices
346175177real GDPThe Real Gross Domestic Product adjusted for inflation gross domestic in a year divided by the GDP price index for that year, index expressed as a decimal.
346175178consumer price index (CPI)a measure of the overall cost of the goods and services bought by a typical consumer
346175179indexationthe automatic correction by law or contract of a dollar amount for the effects of inflation
346175180inflation ratethe percentage change in the price index from the preceding period
346175181nominal interest ratethe interest rate as usually reported without a correction for the effects of inflation
346175182producer price indexa measure of the cost of a basket of goods and services bought by firms
346175183real interest ratethe interest rate corrected for the effects of inflation
346175184catch-up effectthe property whereby countries that start off poor tend to grow more rapidly than countries that start off rich
346175185diminishing returnsthe property whereby the benefit from an extra unit of an input declines as the quantity of the input increases
346175186human capitalthe knowledge and skills that workers acquire through education, training, and experience
346175187natural resourcesthe inputs into the production of goods and services that are provided by nature, such as land, rivers, and mineral deposits
346175188physical capitalthe stock of equipment and structures that are used to produce goods and services
346175189productivitythe quantity of goods and services produced from each unit of labor input
346175190technological knowledgesociety's understanding of the best ways to produce goods and services
346175191bonda certificate of indebtedness
346175192budget deficita shortfall of tax revenue from government spending
346175193budget surplusan excess of tax revenue over government spending
346175194crowding outa decrease in investment that results from government borrowing
346175195financial intermediariesfinancial institutions through which savers can indirectly provide funds to borrowers
346175196financial marketsfinancial institutions through which savers can directly provide funds to borrowers
346175197financial systemthe group of institutions in the economy that help to match one person's saving with another person's investment
346175198market for loanable fundsthe market in which those who want to save supply funds and those who want to borrow to invest demand funds
346175199mutual fundan institution that sells shares to the public and uses the proceeds to buy a portfolio of stocks and bonds
346175200national saving (saving)the total income in the economy that remains after paying for consumption and government purchases
346175201private savingthe income that households have left after paying for taxes and consumption
346175202public savingthe tax revenue that the government has left after paying for its spending
346175203stocka claim to partial ownership in a firm
346175204compoundingthe accumulation of a sum of money in, say, a bank account, where the interest earned remains in the account to earn additional interest in the future
346175205diversificationthe reduction of risk achieved by replacing a single risk with a large number of smaller, unrelated risks
346175206efficient markets hypothesisthe theory that asset prices reflect all publicly available information about the value of an asset
346175207financethe field that studies how people make decisions regarding the allocation of resources over time and the handling of risk
346175208firm-specific riskrisk that affects only a single company
346175209fundamental analysisthe study of a company's accounting statements and future prospects to determine its value
346175210future valuethe amount of money in the future that an amount of money today will yield, given prevailing interest rates
346175211informational efficiencythe description of asset prices that rationally reflect all available information
346175212market riskrisk that affects all companies in the stock market
346175213present valuethe amount of money today that would be needed, using prevailing interest rates, to produce a given future amount of money
346175214random walkthe path of a variable whose changes are impossible to predict
346175215risk aversiona dislike of uncertainty
346175216collective bargainingthe process by which unions and firms agree on the terms of employment
346175217cyclical unemploymentthe deviation of unemployment from its natural rate
346175218discouraged workersindividuals who would like to work but have given up looking for a job
346175219efficiency wagesabove-equilibrium wages paid by firms to increase worker productivity
346175220frictional unemploymentunemployment that results because it takes time for workers to search for the jobs that best suit their tastes and skills
346175221job searchthe process by which workers find appropriate jobs given their tastes and skills
346175222labor forcethe total number of workers, including both the employed and the unemployed
346175223labor-force -participation ratethe percentage of the adult population that is in the labor force
346175224natural rate of unemploymentthe normal rate of unemployment around which the unemployment rate fluctuates
346175225strikethe organized withdrawal of labor from a firm by a union
346175226structural unemploymentunemployment that results because the number of jobs available in some labor markets is insufficient to provide a job for everyone who wants one
346175227unemployment insurancea government program that partially protects workers' incomes when they become unemployed
346175228unemployment ratethe percentage of the labor force that is unemployed
346175229uniona worker association that bargains with employers over wages, benefits, and working conditions
346175230central bankan institution designed to oversee the banking system and regulate the quantity of money in the economy
346175231commodity moneymoney that takes the form of a commodity with intrinsic value
346175232currencythe paper bills and coins in the hands of the public
346175233demand depositsbalances in bank accounts that depositors can access on demand by writing a check
346175234discount ratethe interest rate on the loans that the Fed makes to banks
346175235federal funds ratethe interest rate at which banks make overnight loans to one another
346175236Federal Reserve (Fed)the central bank of the United States
346175237fiat moneymoney without intrinsic value that is used as money because of government decree
346175238fractional-reserve bankinga banking system in which banks hold only a fraction of deposits as reserves
346175239liquiditythe ease with which an asset can be converted into the economy's medium of exchange
346175240medium of exchangean item that buyers give to sellers when they want to purchase goods and services
346175241monetary policythe setting of the money supply by policymakers in the central bank
346175242moneythe set of assets in an economy that people regularly use to buy goods and services from other people
346175243money multiplierthe amount of money the banking system generates with each dollar of reserves
346175244money supplythe quantity of money available in the economy
346175245open-market operationsthe purchase and sale of U.S. government bonds by the Fed
346175246reserve ratiothe fraction of deposits that banks hold as reserves
346175247reserve requirementsregulations on the minimum amount of reserves that banks must hold against deposits
346175248reservesdeposits that banks have received but have not loaned out
346175249store of valuean item that people can use to transfer purchasing power from the present to the future
346175250unit of accountthe yardstick people use to post prices and record debts
346175251classical dichotomythe theoretical separation of nominal and real variables
346175252Fisher effectthe one-for-one adjustment of the nominal interest rate to the inflation rate
346175253inflation taxthe revenue the government raises by creating money
346175254menu coststhe costs of changing prices
346175255monetary neutralitythe proposition that changes in the money supply do not affect real variables
346175256nominal variablesvariables measured in monetary units
346175257quantity equationthe equation M × V = P × Y relates the quantity of money, the velocity of money, and the dollar value of the economy's output of goods and services
346175258quantity theory of moneya theory asserting that the quantity of money available determines the price level and that the growth rate in the quantity of money available determines the inflation rate
346175259real variablesvariables measured in physical units
346175260shoeleather coststhe resources wasted when inflation encourages people to reduce their money holdings
346175261velocity of moneythe rate at which money changes hands
346175262appreciationan increase in the value of a currency as measured by the amount of foreign currency it can buy
346175263balanced tradea situation in which exports equal imports
346175264closed economyan economy that does not interact with other economies in the world
346175265depreciationa decrease in the value of a currency as measured by the amount of foreign currency it can buy
346175266net capital outflowthe purchase of foreign assets by domestic residents minus the purchase of domestic assets by foreigners
346175267net exportsthe value of a nation's exports minus the value of its imports; also called the trade balance
346175268nominal exchange ratethe rate at which a person can trade the currency of one country for the currency of another
346175269open economyan economy that interacts freely with other economies around the world
346175270purchasing-power paritya theory of exchange rates whereby a unit of any given currency should be able to buy the same quantity of goods in all countries
346175271real exchange ratethe rate at which a person can trade the goods and services of one country for the goods and services of another
346175272trade balancethe value of a nation's exports minus the value of its imports; also called net exports
346175273trade deficitan excess of imports over exports
346175274trade surplusan excess of exports over imports
346175275capital flighta large and sudden reduction in the demand for assets located in a country
346175276trade policya government policy that directly influences the quantity of goods and services that a country imports or exports
346175277aggregate-demand curvea curve that shows the quantity of goods and services that households, firms, the government, and customers abroad want to buy at each price level
346175278aggregate-supply curvea curve that shows the quantity of goods and services that firms choose to produce and sell at each price level
346175279depressiona severe recession
346175280model of aggregate demand and aggregate supplythe model that most economists use to explain short-run fluctuations in economic activity around its long-run trend
346175281natural rate of outputthe production of goods and services that an economy achieves in the long run when unemployment is at its normal rate
346175282recessiona period of declining real incomes and rising unemployment
346175283stagflationa period of falling output and rising prices
346175284automatic stabilizerschanges in fiscal policy that stimulate aggregate demand when the economy goes into a recession without policymakers having to take any deliberate action
346175285crowding-out effectthe offset in aggregate demand that results when expansionary fiscal policy raises the interest rate and thereby reduces investment spending
346175286fiscal policythe setting of the level of government spending and taxation by government policymakers
346175287multiplier effectthe additional shifts in aggregate demand that result when expansionary fiscal policy increases income and thereby increases consumer spending
346175288theory of liquidity preferenceKeynes's theory that the interest rate adjusts to bring money supply and money demand into balance
346175289natural-rate hypothesisthe claim that unemployment eventually returns to its normal, or natural, rate, regardless of the rate of inflation
346175290Phillips curvea curve that shows the short-run trade-off between inflation and unemployment
346175291rational expectationsthe theory that people optimally use all the information they have, including information about government policies, when forecasting the future
346175292sacrifice ratiothe number of percentage points of annual output lost in the process of reducing inflation by 1 percentage point
346175293supply shockan event that directly alters firms' costs and prices, shifting the economy's aggregate-supply curve and thus the Phillips curve

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