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Organic Chemistry Lecture 18

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Subject: 
Chemistry
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SocialTags: 
Chemistry
Organic chemistry
Functional groups
Ketone
Carbonyl group
Aldehyde
Grignard reaction
Wittig reaction
Hemiacetal
Acetal
Alkene
Alcohol

Chapter 18 ?2010, Prentice Hall Organic Chemistry, 7th Edition L. G. Wade, Jr. Ketones and Aldehydes Chapter 18 * Carbonyl Compounds Chapter 18 Chapter 18 * Carbonyl Structure Carbon is sp2 hybridized. C?O bond is shorter, stronger, and more polar than C?C bond in alkenes. Chapter 18 Chapter 18 * Ketone Nomenclature Number the chain so that carbonyl carbon has the lowest number. Replace the alkane -e with -one. 3-methyl-2-butanone 4-hydroxy-3-methyl-2-butanone C H 3 C O C H C H 3 C H 3 C H 3 C O C H C H 3 C H 2 O H 1 2 3 4 1 2 3 4 Chapter 18 Chapter 18 * Ketone Nomenclature (Continued) For cyclic ketones, the carbonyl carbon is assigned the number 1. 3-bromocyclohexanone O B r 1 3 Chapter 18 Chapter 18 * C H 3 C H 2 C H C H 3 C H 2 C H O Aldehydes Nomenclature

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