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Grignard reaction

Organic Chemistry Lecture 18

Subject: 
Chemistry
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Chemistry
Organic chemistry
Functional groups
Ketone
Carbonyl group
Aldehyde
Grignard reaction
Wittig reaction
Hemiacetal
Acetal
Alkene
Alcohol

Chapter 18 ?2010, Prentice Hall Organic Chemistry, 7th Edition L. G. Wade, Jr. Ketones and Aldehydes Chapter 18 * Carbonyl Compounds Chapter 18 Chapter 18 * Carbonyl Structure Carbon is sp2 hybridized. C?O bond is shorter, stronger, and more polar than C?C bond in alkenes. Chapter 18 Chapter 18 * Ketone Nomenclature Number the chain so that carbonyl carbon has the lowest number. Replace the alkane -e with -one. 3-methyl-2-butanone 4-hydroxy-3-methyl-2-butanone C H 3 C O C H C H 3 C H 3 C H 3 C O C H C H 3 C H 2 O H 1 2 3 4 1 2 3 4 Chapter 18 Chapter 18 * Ketone Nomenclature (Continued) For cyclic ketones, the carbonyl carbon is assigned the number 1. 3-bromocyclohexanone O B r 1 3 Chapter 18 Chapter 18 * C H 3 C H 2 C H C H 3 C H 2 C H O Aldehydes Nomenclature

Organic Chemistry Lecture 10

Subject: 
Chemistry
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0
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SocialTags: 
Chemistry
Organic chemistry
Functional groups
Alcohol
Grignard reaction
Ketone
Carbonyl reduction
Ester
Carboxylic acid
Carbonyl group
Organolithium reagent
Alkene

Chapter 10 ?2010, Prentice Hall Organic Chemistry, 7th Edition L. G. Wade, Jr. Structure and Synthesis of Alcohols Chapter 10 * Structure of Water and Methanol Oxygen is sp3 hybridized and tetrahedral. The H?O?H angle in water is 104.5?. The C?O?H angle in methyl alcohol is 108.9?. Chapter 10 Chapter 10 * Classification of Alcohols Primary: carbon with ?OH is bonded to one other carbon. Secondary: carbon with ?OH is bonded to two other carbons. Tertiary: carbon with ?OH is bonded to three other carbons. Aromatic (phenol): ?OH is bonded to a benzene ring. Chapter 10 Chapter 10 * Examples of Classifications C H 3 C C H 3 C H 3 O H * C H 3 C H O H C H 2 C H 3 * C H 3 C H C H 3 C H 2 O H * Primary alcohol Secondary alcohol Tertiary alcohol Chapter 10 Chapter 10 *
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