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A2 Organic Chemistry Reactions, Reagents and Conditions Flashcards

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5724798878Change of Functional Group in "Oxidation of Aldehydes".Aldehyde to Carboxylic Acid0
5724812033Reagent in "Oxidation of Aldehydes"Potassium dichromate (VI) solution and dilute sulphuric acid1
5724815289Conditions of "Oxidation of Aldehydes"Heat under Reflux2
5724822838Forming Tollen's ReagentAqueous Ammonia and Silver Nitrate.3
5724829089Complex Ion in Tollen's Reagent[Ag(NH3)2]+4
5724839039Conditions for Tollen's ReagentHeat Gently.5
5724845727Tollen's Reagent vs Aldehyde Chemical ChangesOxidised into a carboxylic acid and silver (I) ions are reduced to silver atoms.6
5724857179Tollen's Reagent vs Aldehyde Observation.SIlver Mirror forms.7
5724859624Tollen's Reagent vs KetoneNo change.8
5724868124Fehling's Solution ConditionsHeat Gently9
5724874952Fehling's Solution vs Aldehyde Chemical ChangesOxidised into a carboxylic acid and copper ions are reduced to copper (I) oxide.10
5724882485Fehling's Solution vs Aldehyde Observation.Blue Cu2+ ions in solution change to red precipitate of Cu2O.11
5724904605Fehling's Solution vs KetoneNo reaction.12
5724907150Reduction of Carbonyls ReagentsNaBH4 in aqueous ethanol13
5724917093Reduction of Carbonyls ConditionRoom temperature and pressure.14
5724929060What does Catalytic Hydrogenation do?Reduce Carbonyls.15
5724932324Catalytic Hydrogenation ReagentHydrogen and nickel catalsyt.16
5724953078Catalytic Hydrogenation ConditionHigh Pressure17
5734537917Carbonyl to Hydroxynitriles ReagentSodium Cyanide (NaCN) and dilute Sulphuric Acid18
5734552542Carbonyl to Hydroxynitriles ConditionsRoom temperature and pressure19
5734563694Carbonyl to Hydroxynitriles MechanismNucleophilic Addition20
5734624827Hydrolysis of Ester using Acid ReagentsDilute Acid HCl21
5734630164Hydrolysis of Ester using Acid ConditionsHeat under Reflux22
5734631554Hydrolysis of Ester using Alkali ReagentsDilute Sodium Hydroxide23
5734647247Hydrolyiss of Ester using Alkali ConditionsHeat under Reflux24
5734658518Acyl Chlorides Reaction with Water Change in Functional GroupAcyl Chloride -> Carboxylic Acid25
5734671303Acyl Chlorides Reaction with Water ReagentWater26
5734671304Acyl Chlorides Reaction with Water ConditionsRoom Temperature27
5734686286Acid Anhydrides Reaction with Water Change in Functional GroupAcid Anhydride -> Carboxylic Acid28
5734688840Acid Anhydrides Reaction with Water ReagentWater29
5734690937Acid Anhydrides Reaction with Water ConditionsRoom temp.30
5734697935Acyl Chlorides Reaction with Alcohol Change in Fuctional GroupAcyl Chloride -> Water31
5734700734Acyl Chlorides Reaction with Alcohol ReagentAlcohol32
5734700735Acyl Chlorides Reaction with Alcohol ConditionsRoom Temperature33
5734707198Acid Anhydride Reaction with Alcohol Change in Fuctional GroupAcid Anhydride -> Ester34
5734712047Acid Anhydride Reaction with Alcohol ReagentAlcohol35
5734712050Acid Anhydride Reaction with Alcohol ConditionsRoom Temperature36
5734735744Acyl Chlorides Reaction with Ammonia Change in Functional GroupAcyl Chloride -> Primary Amide37
5734743262Acyl Chlorides Reaction with Ammonia ReagentAmmonia38
5734743346Acyl Chlorides Reaction with Ammonia ConditionsRoom Temperature39
5734781588Acid Anhydride Reaction with Ammonia Change in Fuctional GroupAcid Anhydride -> Primary Amide40
5734783660Acid Anhydride Reaction with Ammonia ReagentAmmonia41
5734791056Acid Anhydride Reaction with Ammonia ConditionsRoom Temperature42
5734796570Acyl Chlorides Reaction with Primary Amines Change in Functional GroupAcyl Chloride -> Secondary Amine43
5734799988Acyl Chlorides Reaction with Primary Amines ReagentPrimary Amine44
5734799989Acyl Chlorides Reaction with Primary Amines ConditionsRoom Temperature45
5734806875Acid Anhydride Reaction with Primary Amines Change in Functional GroupAcid Anhydride -> Secondary Amide46
5734808827Acid Anhydride Reaction with Primary Amines ReagentPrimary Amine47
5734808828Acid Anhydride Reaction with Primary Amines ConditionsRoom Temp.48
5734823428Nitration of Benzene Change in Fuctional GroupBenzene -> Nitrobenzene49
5734826955Nitration of Benzene ReagentsConc. nitric acid in the presence of concentrated sulphuric acid (catalyst).50
5734830110Nitration of Benzene MechanismElectrophilic Substituion51
5734832337Nitration of Benzene ElectrophileNO2+52
5734843359Friedel Crafts Acylation Change in Functional GroupBenzene -> phenyl ketone53
5734847388Friedel Crafts Acylation ReagentsAcyl chloride in presence of anhydrous aluminium chloride catalyst54
5734853889Friedel Crafts Acylation ConditionsHeat under Reflux (50c)55
5734863966Friedel Crafts Acylation MechanismElectrophilic Substituion56
5734869064Reducing a Nitroarene to Aromatic Amines ReagentSn and HCl or Fe and HCl57
5734872495Reducing a Nitroarene to Aromatic Amines ConditionsHeating58
5734872562Reducing a Nitroarene to Aromatic Amines MechanismReduction59
5734889199Preparing Amines from Nitriles: Step 1 and reagents/conditionsConvert Haloalkane to Nitrile using KCN in ethanol (heat under reflux)60
5734894449Preparing Amines from Nitriles: Step 2 and reagents/conditionsReduce nitrile to amine by using LiAlH4 in ether or by reducing with H2 using a Ni catalyst.61
5734948450Acid + MetalSalt + Hydrogen62
5734950627Acid + AlkaliSalt + Water63
5734950630Acid + CarbonateSalt + Water + Carbon Dioxide.64
5734962550Nitration of Benzene Equation for Formation of ElectrophileHNO3 + 2H2SO4 -> (NO2+) +(2HSO4-) +(H3O+)65
5734988052Friedel Craft Acylation Equation for Formation of the electrophileAlCl3 + Ch3COCl -> CH3CO+AlC4-66
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