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Bio AP: Cellular Energetics Flashcards

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6676294897Where is energy stored in glucose, starch, fat, etcIn the chemical bonds -cells release energy when bonds are broken0
6676303055bioenergeticsthe study of how cells obtain, store and release energy1
6676324478what happens to energy when bonds are formedenergy is used2
6676328108what happens to energy when bonds are brokenenergy is released -but it takes energy to break the bonds3
6676334115enzymes-protein molecules that catalyze chemical reactions to speed up chemical reactions -decrease the amount of energy the cell needs to expend4
6676343003organic catalysts-enzymes -they speed up the rate of a reaction without altering the reaction itself5
6676350370do enzymes change during the reactions they catalyzeno6
6676350371exergonic reactions-energy is released -the products have more energy than the reactants7
6676511077endergonic reaction-require an input of energy -products have more energy than reactants8
6676523871activation energy-the energy barrier -the amount of energy required to get a reaction started9
6676535441do exergonic reactions require activation energy?yes10
6676766588what does it mean to catalyze a reaction-to activatae a reaction and to lower the activation energy of a reaction, enabling the reaction to occur much faster than it would in the absence of a catalyst11
6676776311enzyme specificity-each enzyme only catalyzes one type of reaction -shape determines function -enzymes are named after the molecules they target12
6676783673substratesthe molecules that are catalyzed by an enzyme13
6676790119what does the suffix -ase meanusually means enzyme14
6676795757active sitethe region on an enzyme where the substrates are brought together15
6676798935enzyme-substrate complexthe structure formed by an enzyme and its substrates binded to the active site16
6676809967what is the outcome of an enzyme-catalyzed reaction calledproduct17
6676814824what happens to the enzyme when the substrate is releasedit's ready for another substrate18
6676823115are enzymes affected in any way by the reactions they catalyzeno19
6676824997do enzymes change the reactions they catalyzeno20
6676829940do enzymes make reactions occur that would otherwise not occur at all?no -just speed them up21
6676829941induced fit-enzyme has to slightly change its shape to accommodate the shape of the substrates' -snug fit22
6676856835coenzymesfactors that help enzymes in catalyzing a reaction -they accept electrons and pass them along to another substrate -ex. NAD+ and NADP+23
6677003958cofactorsinorganic elements that help catalyze reactions -usually metal ions (Fe 2+)24
6677696506what is an important cofactor of hemoglobinFe 2+ because it is important for binding with oxygen in bloodstream25
6677705212three factors that can affect enzyme reaction rates-pH -temp -relative amounts of enzyme and substrate26
6677714334why does an increase in temperature usually increase the rate of a reactionbecuase up to a point, an increase in temp increases the chance of collisions among molecules27
6677720766what can happen if an enzyme is exposed to too much heatthe heat can damage the enzyme -the enzyme loses its 3d shape and becomes inactive28
6677723250denature-when an enzyme loses its shape and therefore its function29
6677730531ideal tempall enzymes operate at an ideal temperature30
6677740429check the equation for Q10 on pg 13531
6677743047what is the optimal pH for most enzymesat or near 732
6677746960what regulates the activity of enzymesthe cell can control enzymatic activity33
6677749377how o cells regulate enzymatic activityby regulating the conditions that influence the shape of the enzyme34
6677750951allosteric sitea region of the enzyme other than the active site to which a substance can bind -allosteric regulators can eithether inhibit or activate enzymes by binding to the allosteric site35
6677753652two types of allosteric regulators-allosteric inhibitor -allosteric activator36
6677765822allosteric inhibitor-binds to an allosteric site and keeps the enzyme in its inactive form37
6677769137allosteric activatorbinds to an enzyme and induces its active form38
6677772438feedback inhibitionthe formation of an endproduct inhibits an earlier reaction in the sequence39
6677778926how do allosteric enzymes relate to feedback inhibition-when there is excess product, the allosteric inhibitor will inactivate the enzyme that produces that product40
6677790190competitive inhiition-when chemical substances that fit into the active site of an enzyme compete with the substrate and effectively inactivate the enzyme -structurally similar to the normal substrate41
6678479746noncompetetive inhibition-the inhibitor binds with the enzyme at a site OTHER than the active site and inactivates the enzyme by altering its shape -prevents the enzyme from binding witht he substrate at the active site42
6678487774first law of thermodynamics (fundamental principle of energy)energy cannot be created nor destroyed. sum of the energy in the universe is constant43
6678490589second law of thermodynamicsstates that energy transfer leads to less organization -the universe tends toward disorder44
6678495058entropydisorder45
6678497520Gibbs Free energydelta G= delta H- TdeltaS46
6678502302enthalpythe measure of energy in a thermodynamic system47
6678504285favorable reaction-spontaneous, and negative free energy48
6678505246unfavorable reactionnonspontaneous, positive free energy49
6678508645what is the gibbs free energy equation used forto figure out if the reactants of a reaction will stay as they are or be converted to products50
6678513109spontaneous reactions-occur without a net addition of energy -have a negative delta G -occur with energy to spare -exergonic51
6678516927nonspontaneous reactions-positive delta G -require energy to be added -endergonic52
6678525362what is the source of energy in living thingsATP53
6678525363ATP acronymadenosine triphosphate54
6678527398structure of ATP-consists of a molecule of adenosine bonded to three phosphates -lots of energy packed into the third phosphate bond55
6678532252How does a cell harvest energy from ATP when it needs energy-it takes a molecule of ATP and splits off the third phosphate, forming adenosine diphosphate, and one loose phosphate, while releasing energy in the process56
6678539456equation of breaking ATPATP --> ADP + Pi + energy57
6678545036what are two ways that ATP is produced1. cellular respiration 2. photosynthesis58
6678546137photosynthesis-involves the transformation of solar energy inot chemical energy -plants take co2 h20, and energy (sunlight) and use them to produce glucose59
6678550178overall reaction of photosynthesis6CO2 + 6H20 + sunlight --> C6H12O6 + 6O260
6678555467cellular respiration-performed by all organisms -ATP is produced through the breakdown of nutrients61
6678559486equation of cellular respirationC6H12O6 + 6O2 --> 6CO2 + 6H2O + ATP62
6678566144two different forms of cellular respirationaerobic respiration anaerobic respiration63
6678568470whats the difference between aerobic and anaerobic respirationaerobic cellular respiration occurs in the presence of oxygen. anaerobic respiration occurs when oxygen isn't present64
6678571646four stages of aerobic cellular respiration1. glycolysis 2. formation of acetyl CoA 3. the Krebs cycle (Citric Acid cycle) 4. oxidative phosphorylation65
6678575251whats another name for the krebs cyclecitric acid cycle66
6678578789Glycolysis-splitting glucose -glucose is a six-carbon sugar and it gets broken down into two 3-carbon molecule67
6678581849what are the products of glycolysis2 pyruvic acids (3-carbon molecule) 2 NADH68
6678585837how much NET atp is produced during glycolysisnet production of 2 atp69
6678587747equation of glycolysisglucose + 2ATP +2NAD+ --> 2 Pyruvic acid +4ATP + 2NADH70
6678592281What coenzyme is used in cellular respirationNADH and NAD+71
6678595316phosphorylatedmeans to attatch an inorganic phosphate from ATP, and it gives energy72
6678597523does glycolysis happen in one step-no -takes multiple reactions that are each catalyzed by a different enzyme -ATP is required to phosphorylate glucose -NADH is used to transfer electrons73
6678628027how is NADH produced in glycolysis-the transfer of H+ to the hydrogen carrier NAD+, which becomes NADH -NADH will be used later to make ATP74
6678631420where does glycolysis occur-in hte cytoplasm of hte cell75
6678635000what are the cell's two options in cellular respiration after glycolysis is completed-it can continue anaerobic cellular respiration -or it can switch to aerobic cellular respiration76
6678637329is glycolysis aerobic or anaerobicanaerobic bc no oxygen required77
6678653918membrane of the mitochondriahas a double membrane with intermembrane space78
6678645350where does cellular respiration occur after glycolysisin the mitochondria79
6678646915mitochondria matrixinner part of the inner membrane80
6678650628inner mitochondrial membranethe inside membrane of the mitochondria81
6678656592cristaethe folds of the inner membrane82
6681843794outer membrannethe outer membrane of the mitochondria83
6681849848formation of acetyl CoAWhen oxygen is present, pyruvic acid is transported to the mitochondrion, each pyruvic acid is converted to acetyl coenzyme A and CO2 is released84
6681864033acetyl coenzyme Aa two carbon molecule that is produced form pyruvic acid85
6681883948equation of the formation of acetyl coA2pyruvic acid + 2 Coenzyme A + 2NAD+ --> 2 Acetyl CoA + 2CO2 + 2NADH86
6681898993transformation of carbon molecules from glycolysis to formation of acetyl coA-one 6-carbon molecule (glucose) - two 3-carbon molecules (pyruvic acid) -two 3-carbon molecules + 2 CO287
6681919951where do the two extra carbons from pyruvic acid go when acetyl coA is formedthey leave the cell in the form of CO288
6681922564Krebs cycleaka the citric acid cycle -each of the two acetyl coA molecules enter the Krebs cycle, one at a time, and all the carbons ultimately are converted to CO289
6681929185where does the Krebs cycle occurin the matrix of the mitochondria90
6681953783first step of the Krebs cycle-each molecule of acetyl CoA combines with oxaloacetate to form a 6-carbon molecule, citric acid91
6681960735how is citric acid formed-acetyl coA combines with oxaloacetate92
6681964075oxaloacetatea four carbon molecule -combines with acetyl CoA to form citric acid at the beginning of the Krebs cycle -first molecule of the krebs cycle93
6681993133after the formation of citric acid, how many carbons have to be lost to keep the cycle going2 carbons, because the cycle starts with oxaloacetate, a 4-carbon molecule, and citric acid is a 6-carbon molecule94
6682013945how are carbons released during the citric acid cycleas CO295
6682018644what is produced at each turn of the citric acid cycle- 1 ATP - 3 NADH - 1 FADH296
6682028234how many cycles of the krebs cycle occur for each glucose molecule in cellular respiration2, becuase the krebs cycle starts with two acetyl coA molecules97
6682041747How many total ATP are made during the krebs cycle from one glucose, how many ATP are made from one glucose by the Krebs cycle (aslo glycolysis)- 2 during krebs cycle - 4 total in krebs + glycolysis98
6682048337oxidative phosphorylation-electrons are transferred from electron carriers to oxygen, resulting in ATP synthesis99
6682053133electron carriers-NAD+ and FAD -they carry electrons from different stages of cellular respiration -also called hydrogen carriers100
6682066395electron transport chain-energy-rich electrons are taken from the hydrogen carriers to the electron transport chain via electron carriers -hydrogen atoms are split into hydrogen ions and electrons101
6682128532how many loaded electron carriers have been produced during krebs, formation of acetyl coA, and glycolysis- 2 NADH from glycolysis - 2 NADH from production of acetyl CoA -6 NADH from the Krebs cycle -2 FADH2 from the Krebs cycle =12102
6682152596what happens to the hydrogens and electrons from the electron carriers in the electron transport chain-hydrogen atoms are split into hydrogen ions and electrons103
6682157551equation of splitting hydrogen atoms during electron transport chainH2 --> 2H+ + 2e-104
6682165502what is the electron transport chain made ofa series of protein carrier molecules that are embedded in the cristae and the the inner membrane of hte mitochondria105
6682170731where does the electron transport chain occurin the cristae and inner membrane of the mitochondria106
6682174503cytochromes-iron-containing carrier molecules in the electron transport chain107
6682192657what happens to electrons as they travel down the electron transport chaineach carrier molecule hands down electrons to the next molecule in the chain, until the electrons meet the final electron acceptor108
6682200949what is the final electron acceptor in oxidative phosphorylationoxygen109
6682204358what happens when oxygen combines with electrons from the electron transport chain-oxygen , electorns, and some hydrogens combine to form WATER110
6682213726what is the final product of the electron transport chain (before chemiosmosis)water111
6682215993chemiosmosishappens at the same time that electrons go through the electron transport chain112
6682239308what happens to the split Hydrogen ions that split from the electrons-some of the energy from the electron transport chain is used to pump H+ ions across the inner mitochondrial membrane to the intermembrane space113
6682247891pH gradient in chemiosmosis (aka)-the pumpin of hydrogen ions into the intermembrane space creates a pH gradient -aka proton gradient114
6682268328where are the H+ ions when the split from the hydrogen atomin the intermembrane space115
6682272730where do H+ ions have to go TO to produce ATPto the matrix, through the inner membrane116
6682277153how is ATP produce by the proton pumpthere is proton gradient, and the H+ molecules have to get from the low pH where there is a high H+ gradient in the intermembrane space to thte hight pH, where there is a low H+ concentration in the matrix -to do this, they have to pass through channels in the innermembrane called ATP synthase117
6682289625ATP synthase-motor channel proteins in the inner membrane that allow H+ ions to go from the intermembrane space to the matrix -ADP and Pi are in the matrix (other side from H+), and the flow of protons through ATP synthase produces ATP by combining ADP an dPi on the matrix side of the channel118
6682305650what happens in oxidative phosphorylationthe production of ATP with ATP synthase and the H+ proton gradient119
6682317375how many ATPs does each NADH yeild-each NADH produces 3 ATP -except the NADH from glycolysis only makes 2 ATP120
6682323636how many ATP does each FADH2 produce2 ATP121
6682328179what is the total number of ATP produced during oxidative phosphorylation and chemiosmosis32122
6682328180what is the overall net production of ATP during aerobic cellular respiration38 ATP123
6682358187what happens if organisms dont have oxygen to do aerobic cellular respirationthey undergo anaerobic cellular resperation124
6682364978why cant organisms undergo aerobic cellular respiration if there's no oxygenbecause oxygen is required to be the final electron acceptor125
6682371493how do anaerobic organisms get energy-they can undergo glycolysis (make 2 ATP's) -but instead of doing the Krebs cycle, electron transport chain, and oxidative phosphorylation, they do fermenttion126
6682401728fermentationpyruvic acid is converted to either lactic acid or ethyl alcohol and co2127

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