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Stereoisomerism

Organic Chapter 5 ppt

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Chemistry
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Chemistry
Stereochemistry
Chirality
Diastereomer
Enantiomer
Stereocenter
Stereoisomerism
Isomer
Racemic mixture
Meso compound
Specific rotation
Cahn–Ingold–Prelog priority rules

Chapter 5 Stereochemistry Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 5 * Summary of Isomers => Chapter 5 Chapter 5 * Stereochemistry The study of 3-D structure of molecues. Recall the 2 different types of isomers: Constitutional Stereoisomers Chapter 5 Chapter 5 * Stereoisomers Same bonding sequence. Different arrangement in space. Example: HOOC-CH=CH-COOH has two geometric (cis-trans) isomers: o o => Chapter 5 Chapter 5 * Chirality ?Handedness?: right glove doesn?t fit the left hand. Mirror-image object is different from the original object. Relationship ? the objects are nonsuperimposable (nonidentical) mirror images. Chapter 5 Chapter 5 * Chirality in Molecules The cis isomer is achiral (?not handed? or identical with its mirror image).

Stereo chemistry of organic compounds

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Chemistry
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Chemistry
Stereochemistry
Isomerism
Chemical nomenclature
Physical organic chemistry
Chemical formulas
Isomer
Cyclohexane conformation
Cahn–Ingold–Prelog priority rules
Stereoisomerism
Chirality
Alkane
Stereo chemistry

Organic Chemistry Stereochemistry of Organic Compounds Dr. Anita Tandon University of Delhi Delhi -110007 CONTENTS Structural Isomers Stereoisomers Conformational Isomers Configurational Isomers (i) Optical isomers (a) Compound with one Asymmetric Carbon Atom (b) Compound with more than one Asymmetric Carbon Atom (c) Compound with no Asymmetric Carbon Atom (d) Elements of Symmetry (e) Properties of Enantiomers (f) Relative Configuration (g) Absolute Configuration (h) Fischer?s Plane Projection Diagram (i) Optical inactivity in compounds having Chiral Carbon Atom (ii) Geometrical Isomers (a) E&Z system of nomenclature (b) Properties of Geometrical Isomers
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