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Physical organic chemistry

Psyc Ch. 4

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Alcohols and Alkyl Halides: Introduction to Reaction Mechanisms In this chapter we explore structure and reactivity in more detail by developing two concepts: functional groups and reaction mechanisms. A functional group is the atom or group in a molecule most responsible for the reaction the compound undergoes under a prescribed set of conditions. How the structure of the reactant is transformed to that of the product is what we mean by the reaction mechanism. 4.1 Functional Groups Table 4.1 lists the major families of organic compounds covered in this text and their functional groups. 4.2 IUPAC Nomenclature of Alkyl Halides The IUPAC rules permit alkyl halides to be named in two different ways, called functional class

Stereo chemistry of organic compounds

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Organic Chemistry Stereochemistry of Organic Compounds Dr. Anita Tandon University of Delhi Delhi -110007 CONTENTS Structural Isomers Stereoisomers Conformational Isomers Configurational Isomers (i) Optical isomers (a) Compound with one Asymmetric Carbon Atom (b) Compound with more than one Asymmetric Carbon Atom (c) Compound with no Asymmetric Carbon Atom (d) Elements of Symmetry (e) Properties of Enantiomers (f) Relative Configuration (g) Absolute Configuration (h) Fischer?s Plane Projection Diagram (i) Optical inactivity in compounds having Chiral Carbon Atom (ii) Geometrical Isomers (a) E&Z system of nomenclature (b) Properties of Geometrical Isomers
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