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Fuel cell

AP Chemistry Zumdahl 7E Chapter 17 Notes

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1 Chapter 17 ? Electrochemistry 17.1 Galvanic Cells A. Oxidation-Reduction Reactions (Redox Rxns) 1. Oxidation = loss of electrons a. the substance oxidized is the reducing agent 2. Reduction = gain of electrons a. the subtance reduced is the oxidizing agent B. Redox energy 1. Heat is produced 2. Electricity can be produced if the reactants are separated a. Reactants can be separated by a salt bridge b. Reactants can be separated by a porous partition c. Electrons travel through a wire C. Galvanic Cell 1. A device in which chemical energy is changed to electrical energy a. Oxidation occurs at the anode b. Reduction occurs at the cathode D. Cell Potential (?cell) 1. The driving force (electromotive force, emf) on the electrons 2. Potential is measured in volts

Incineration

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Further Application of Incineration ? new fuel cell Original fuel cell New fuel cell using incineration waste Waste : fly ash reason: high calcium content (66.8 wt% )for the formation of calcium phosphate hydrogel What is calcium phosphate hydrogel? a type of fast proton conductor, increase the efficiency of fuel cell Calcium phosphate hydrogel (a) Incineration fly ash + phosphoric acid (b) mixture of K2CO3 and CaCO3 reagents (c) CaCO3 reagent Performance of new fuel cell Performance of new fuel cell The performance of the fuel cell containing calcium phosphate hydrogel synthesized from incineration fly ash is almost equal to that of the fuel cell containing a hydrogel membrane obtained from other reagents
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