definition - increases the concentration of OH- ions when dissolved in water
- Bronsted-Lowry definition - accepts proton from another substance
- even applies to substances not dissolved in water
- Lewis definition - electron-pair donor
- pOH = -log [OH-]
- pOH = 14 - pH
- strong base - completely dissociates, [OH-] = [base]
- hydroxides of alkali metals and heavy alkaline earth metals
- weak base - partially dissociates
- Kb = [OH-][conjugate acid] / [base]
- [OH-] = [conjugate acid] when Kb is very small
Find the pH of 0.0030 M solution of ammonia
- Kb = 1.8 x 10-5
- Kb = [OH-] [ammonium] / [ammonia] = x2 / 0.0030
- x = [(1.8 x 10-5) (0.0030)]1/2 = 2.3 x 10-4 = [OH-]
- pOH = -log [OH-] = 3.63
- pH = 14 - 3.63 = 10.37