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Coordination chemistry

AP Chemistry MIDTERM review C

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Zn + N O 3- + H+ ?Zn2+ + N H 4+ + H 2O Which statement about this reaction is correct? The oxidation number of H changes from +1 to 0 The oxidation number of H changes from +1 to -1 The oxidation number of N changes from +5 to -3 The oxidation number of N changes from +5 to +3 The oxidation number of N changes from +6 to +4 Assign oxidation numbers to each element Zinc goes from 0 to +2 (lost 2 electrons) N goes from +5 to -3 (gained 8 electrons) C 100 0 +5 -2 -3 +1 +1 -2 2H2O2(g) + S(s) ? SO2(g) + 2H2O(g) What is the enthalpy change in the reaction? C 200 Substance ?Hf (kJ/mol) H2O2(g) -150 S(s) 0 SO2(g) -300 H2O(g) -250 -500 kJ -200 kJ 200 kJ 400 kJ 600 kJ [2(-250) + (-300) ] ? [2(-150) + 0] = -500 C 300 CH3CH2OH(g) + ___O2(g) ? ___CO2(g) + ___H2O(g)

Chem Ch. 18

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Complex Ions Complex ion - ionic species consisting of a metal ion bonded to one or more Lewis bases Coordinate bond - bond formed when one anion/molecule donates a pair of electrons to another ion/molecule to form a covalent bond Ligand - a Lewis base bonded to the central metal ion of a complex ion Common Ligands (Lewis Bases): NH3, H2O, OH-, Cl-, CN- Inner coordination sphere - ligands that are bound directly to a metal via coordinate covalent bonds Counter ions - ions that balance the electrical charges of complex ions in coordination compounds Ex: [Ag(NH 3 ) 2 ] + + Cl - ?> [Ag(NH 3 ) 2 ]Cl Coordination compound - any compound that contains a complex ion Coordination number - identifies the number of electron pairs surrounding a metal ion in a

Bob Jones PPT Notes -- Chapter 8a

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Chemical Composition &Reactions Oxidation Numbers Keep track of electrons during bonding Tell how many electrons are involved in the bond Tell whether electrons are gained, lost, or unequally shared Oxidation Numbers Help in predicting formulas The more electronegative element gains electrons. The oxidation number of atoms and elements is zero. (free-element) Rule 1 Oxidation Numbers Examples: He ? no bonds O2 ? equal sharing (free-element) Rule 1 Oxidation Numbers The oxidation number of a monatomic ion is equal to the charge of the ion. (ions) Rule 2 Oxidation Numbers Example: Mg loses two electrons, so its charge is +2; therefore, its oxidation number is also +2. (ions) Rule 2 Oxidation Numbers Example: Cl gains one electron, so its charge and oxidation number are ?1. (ions)
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