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Chapter 11 Reactions of Alcohols Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 11 * Types of Alcohol Reactions Dehydration to alkene Oxidation to aldehyde, ketone, acids Substitution to form alkyl halide Reduction to alkane Esterification Tosylation Williamson synthesis of ether => Chapter 11 Chapter 11 * Summary Table => Chapter 11 Chapter 11 * Oxidation States Easy for inorganic salts CrO42- reduced to Cr2O3 KMnO4 reduced to MnO2 Oxidation: loss of H2, gain of O, O2, or X2 Reduction: gain of H2 or H-, loss of O, O2, or X2 Neither: gain or loss of H+, H2O, HX => Chapter 11 Chapter 11 * 1?, 2?, 3? Carbons => Chapter 11 Chapter 11 * Sample Problems (1)
