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thermodynamics

Bob Jones PPT Notes -- Chapter 10c

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Gases and the Mole Gay-Lussac formulated the law of combining volumes. Law of Combining Volumes Gases at the same temperature and pressure react with one another in volume ratios of small whole numbers. Law of Combining Volumes Example 1: H2 + Cl2 2HCl 1 L + 1 L 2 L Law of Combining Volumes Example 2: 2H2 + O2 2H2O 2 L + 1 L 2 L Avogadro?s law The volume of a gas, maintained at a constant temperature and pressure, is directly proportional to the number of moles of the gas. Molar Volume the volume that a mole of gas occupies at standard temperature and pressure Molar Volume 1 mole of ANY gas at STP occupies 22.4 L. Sample Problem 1 What volume would 7 moles of carbon dioxide occupy at STP? = 157 L CO2 7 mol CO2 22.4 L 1 mol Change 228 L of O2 at STP to moles. 470 moles 426 moles

Bob Jones PPT Notes -- Chapter 10b

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Gas Laws Standard Temperature and Pressure (STP) Standard temperature: 0?C or 273 K Standard pressure:1 atm, 760 mm Hg, or 101.3 kPa Boyle?s Law The pressure of a dry gas is inversely proportional to its volume if the temperature is held constant. Inverse Proportion two terms related so that, if one term increases, the other term decreases Boyle?s Law P V , PV = k P1V1 = P2V2 As pressure increases, volume decreases. 6 Chemistry textbook, p. 250 7 Chemistry textbook, p. 250 P1V1 = P2V2 Sample Problem 1 A sample of gas occupies 352 mL at a pressure of 3.17 atm. If the P is reduced to 1.24 atm, what volume will result? (3.17 atm)(352 mL) = (1.24 atm)V2 900 mL = V2 A sample of gas occupies 200 mL at a P of 2.15 atm. If the P is reduced to 1.25 atm, what is V2? 344 mL 537 mL 98 mL 89 mL

Bob Jones PPT Notes -- Chapter 10a

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Properties of Gases Kinetic Theory of Gases Many independent particles Random motion at high speed Separated by great distances Kinetic Theory of Gases Interact only when they collide 5. Elastic collisions Physical Properties of Gases Diffusion Effusion Permeability Compressibility Expansibility Diffusion spontaneous mixing due to particle motion Effusion gas particles passing through a tiny opening into an evacuated area Both diffusion and effusion are directly related to the speed of the gas molecules. rate of effusion for gas 1 Graham?s Law of Effusion rate of effusion for gas 2 = molar mass2 molar mass1 molar massN = 28.02 g/mol Sample Problem 1 Calculate the ratio of effusion rates between nitrogen (N2) and Argon (Ar). molar massAr = 39.95 g/mol rate of effusion for gas 1

Bob Jones PPT Notes -- Chapter 2c

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Section 2C States of Matter Kinetic-Molecular Theory All particles are in motion. Add energy = increase motion. Motion tries to tear apart matter. Attractive forces hold matter together. Attractive ? electrical, between particles Disruptive ? caused by kinetic energy (motion) Balance between these forces determines state. Kinetic-Molecular Theory Two Forces Solid Low energy Touching Locked in place Only vibrate (The inter-molecular forces are higher in energy than the kinetic energy.) 4 p. 41 of Chem. textbook Liquid More kinetic energy Still touching Not locked in place Can roll around (The intermolecular forces are almost equal to the kinetic energy.) 5 p. 41 of Chem. textbook Atoms are touching. Attractions are greater than repulsions. Atoms roll around. Atoms are small.

Bob Jones PPT Notes -- Chapter 2b

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Energy and Matter Energy Energy the ability to do work Work Work a force moving matter through a distance Both energy and work are measured in joules (J). Forms of Energy Mechanical ? objects Kinetic ? moving Potential ? stored Thermal ? kinetic energy of atoms and molecules Forms of Energy Acoustic (sound) ? periodic, wave-like motion of atoms and molecules Electromagnetic ? moving electrons Chemical ? breaking and forming bonds Forms of Energy Nuclear ? from center of atom 6 Energy Conservation Despite Change ?the study of the flow of energy? Thermodynamics ?the law of conservation of mass-energy? (Conservation doesn?t refer to turning off the lights.) First Law of Thermodynamics ?the law of conservation of mass-energy?

Chapter 5

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Chapter 5 ? Gases 5.1- Pressure ~Barometer ? Measures atmospheric pressure. Invented in 1643 Units of Pressure ~Manometer ? instrument used for measuring pressure. MmHg / Torr ~ Standard atmosphere : 1 atm = 760 mmHg = 760 Torr = 101325 Pa 5.2 The Gas Laws of Boyle, Charles, and Avogadro Boyle?s Law- Pressure and volume are INVERSELY PROPORTIONAL P goes up V goes down P1V1 = P2V2 Charles Law- As T increases V increases V1/ T1 = V2/ T2 ~ K = `C + 273 ~ Pgas = Patm + Ph in an open ended manometer Gay- Lussac?s Law- P1/T1 = P2/T2 Avogadro?s Law- V1/n1 = V2/n2 Combined gas law- P1V1/n1T1 = P2V2/n2T2 Ideal Gas Laws- PV = nRT ~Kinetic Molecular Theory of Gases consant motion and perfectly elastic gas molecules do not attract or repel

AP Chemistry Chapter 6 Outline

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Daniel Seo 10/10/13 Period 5 Chapter 6 Thermochemistry Outline 6.1 The Nature of Energy 1. Energy ? capacity to do work (or to produce heat) i. Work ? force acting over a distance (moving an object) ii. Heat ? form of energy. ? chemicals may store potential energy in their bonds that can be released as heat energy 2. The law of conservation of mass ? energy can be converted from one form to another, but cannot be created or destroyed ? is also the first law of thermodynamics. i. Potential energy ? energy due to position or composition ii. Kinetic energy ? energy due to the motion of an object ? K? = 1/2mv2 3. Temperature reflects random motion of particles in a substance 4. Temperature indicates the direction in which heat energy will flow

Chemistry Chapter 1~3

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Lecture 1 (Chapter 1 ~ Chapter 3) Chapter 1 Chemistry ? The?study?of?the?composition,?structure,?and?properties?of?MATTER?and?CHANGES?it?undergoes? Scientific method ? Observation? o Observe? o Gather??Data? ? Qualitative?(Description)? ? Quantitative?(Number?[followed?by?unit])? ? Identify?Problem? o Known? o Unknown? ? Hypothesize? o If_____________?then_______________? ? Test?&?Collect?Data? ? Analyze?Data? ? Theorize? Branch of Chemistry ? Biochemistry? ? Organic?chemistry? ? Inorganic?chemistry? ? Etc.? Significant figures ? All??0?s?between?two?nonzero?=?significant? ? Place?holding??0?s?=?not?significant? ? All?nonzero?=?significant? ? All??0?s?on?the?right?of?the?non??0?s?=?significant? ? All??0?s?on?the?right?of?decimal,?except?place?holders?=?significant?

Chapter 5 Thermochemistry

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Chapter 5: Thermochemistry ?Introduction- Energy is defined as the capacity or the ability the to do work i.e. in order to do work energy must be involved Mathematically Represented- Work or Energy = Force x Distance The view of energy can be thought of as physical in nature and contact via the exerted force Chemistry, however, must view energy differently. The study of energy and its transformation, as it applies to chemistry, is know as THERMOCHEMISTRY, along with spontaneity, the two are referred to as THERMODYNAMICS Section 5.1- Nature of Energy The study of chemistry and thermodynamics will involve the concepts of energy, work, and heat KINETIC and POTENTIAL Energy Kinetic ? energy due to an objects motion

Chemistry Basics (1st half of chemistry books)

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CHAPTER ONE: Mass Kilogram (kg) Balance scale Volume Cubic Meter (m?) Graduated cylinder Temperature Kelvin (K) Thermometer Length Meters (m) Meter stick Time Seconds (sec) Stopwatch Energy Joules (J) (Measured Indirectly) Independent: what you control Dependent: what you measure or observe CHAPTER TWO: Ionic Compounds: 2 elements/ a metal & nonmetal Write the name of the metal (cation) Write the name of the non-metal (anion) with the suffix ?-ide? Polyatomic ions don?t change their name Molecular Compounds: 2 non-metals/ no hydrogen First word= name of first element with no name change Second word= name of second element with ending change to ?-ide? Prefix with mono, di, tri, tetra, penta, hexa, hepta, octa, nona, or deca

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