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Chemical engineering

Chapter 10

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Chapter 10 notes Claire Rafson 10.1-10.2 Intermolecular forces- occur b/w not in molecules. From solid to liquid to gas molecules remain in tact Forces: Dipole-dipole forces are forces that act between polar molecules Hydrogen bonding- strong form of dipole dipole with H and NOF London Dispersion- Present in all but ionic . noble gas and nonpolar and Polar. Big atom with a lot electrons LD can be stronger than dipole dipole Higher IMF = higher: surface tension, boiling/meltin point. Lower: vapor pressure Capillary action- polar liquids typically exhibit it 10.3- crystalline solids- highly regular arrangement of their components ionic and molecular amorphous solids- considerable disorder 10.5- Network atomic Solids- giant molecule Strong covalent bonds Silica- SiO2

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CALIFORNIA STANDARDS TEST CHEMISTRY (Blueprint adopted by the State Board of Education 10/2002) CALIFORNIA CONTENT STANDARDS: CHEMISTRY # of Items % Atomic and Molecular Structure 6 10.0% 1. The periodic table displays the elements in increasing atomic number and shows how periodicity of the physical and chemical properties of the elements relates to atomic structure. As a basis for understanding this concept: a. Students know how to relate the position of an element in the periodic table to its atomic number and atomic mass. 1 b. Students know how to use the periodic table to identify metals, semimetals, non-metals, and halogens. 1

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CALIFORNIA STANDARDS TEST CHEMISTRY (Blueprint adopted by the State Board of Education 10/2002) CALIFORNIA CONTENT STANDARDS: CHEMISTRY # of Items % Atomic and Molecular Structure 6 10.0% 1. The periodic table displays the elements in increasing atomic number and shows how periodicity of the physical and chemical properties of the elements relates to atomic structure. As a basis for understanding this concept: a. Students know how to relate the position of an element in the periodic table to its atomic number and atomic mass. 1 b. Students know how to use the periodic table to identify metals, semimetals, non-metals, and halogens. 1

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CALIFORNIA STANDARDS TEST CHEMISTRY (Blueprint adopted by the State Board of Education 10/2002) CALIFORNIA CONTENT STANDARDS: CHEMISTRY # of Items % Atomic and Molecular Structure 6 10.0% 1. The periodic table displays the elements in increasing atomic number and shows how periodicity of the physical and chemical properties of the elements relates to atomic structure. As a basis for understanding this concept: a. Students know how to relate the position of an element in the periodic table to its atomic number and atomic mass. 1 b. Students know how to use the periodic table to identify metals, semimetals, non-metals, and halogens. 1

Chemistry Chapter 1~3

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Lecture 1 (Chapter 1 ~ Chapter 3) Chapter 1 Chemistry ? The?study?of?the?composition,?structure,?and?properties?of?MATTER?and?CHANGES?it?undergoes? Scientific method ? Observation? o Observe? o Gather??Data? ? Qualitative?(Description)? ? Quantitative?(Number?[followed?by?unit])? ? Identify?Problem? o Known? o Unknown? ? Hypothesize? o If_____________?then_______________? ? Test?&?Collect?Data? ? Analyze?Data? ? Theorize? Branch of Chemistry ? Biochemistry? ? Organic?chemistry? ? Inorganic?chemistry? ? Etc.? Significant figures ? All??0?s?between?two?nonzero?=?significant? ? Place?holding??0?s?=?not?significant? ? All?nonzero?=?significant? ? All??0?s?on?the?right?of?the?non??0?s?=?significant? ? All??0?s?on?the?right?of?decimal,?except?place?holders?=?significant?

Gas laws

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A Gas Uniformly fills any container. Mixes completely with any other gas Exerts pressure on its surroundings. A Gas It might help to define a gas based on the other phases as well. -Movie Clip- Kinetic Molecular Theory 1. Volume of individual particles is ? zero. 2. Collisions of particles with container walls cause pressure exerted by gas. 3. Particles exert no forces on each other. 4. Average kinetic energy ? Kelvin temperature of a gas. The Meaning of Temperature Kelvin temperature is an index of the random motions of gas particles (higher T means greater motion.) -Kinetic Energy Video- Pressure is equal to force/unit area SI units = Newton/meter2 = 1 Pascal (Pa) 1 standard atmosphere = 101,325 Pa 1 standard atmosphere = 1 atm = 760 mm Hg = 760 torr atm mmHg torr

chapter 11 intermolecular forces, liquids, and solids

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? 2009, Prentice-Hall, Inc. Chapter 11 Intermolecular Forces, Liquids, and Solids John D. Bookstaver St. Charles Community College Cottleville, MO Chemistry, The Central Science, 11th edition Theodore L. Brown, H. Eugene LeMay, Jr., and Bruce E. Bursten ? 2009, Prentice-Hall, Inc. ? 2009, Prentice-Hall, Inc. States of Matter The fundamental difference between states of matter is the distance between particles. ? 2009, Prentice-Hall, Inc. ? 2009, Prentice-Hall, Inc. States of Matter Because in the solid and liquid states particles are closer together, we refer to them as condensed phases. ? 2009, Prentice-Hall, Inc. ? 2009, Prentice-Hall, Inc. The States of Matter The state a substance is in at a particular temperature and pressure depends on two antagonistic entities:

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Chemistry Final Review Guide 2012 The 1st Section on the final will be metric conversions, significant figures, and scientific notation. The 2nd Section on the final will be multiple choice questions. There will be 40 of them and they will cover vocabulary and basic chemistry questions. The BEST way to study for this section would be to gather all old chemistry tests and review all of the multiple choice questions The 3rd Section will be calculations split into 3 parts. Part A will focus on writing chemical equations from word equations, balancing them, and then stating what type of reaction it is. For example: 1. Solid aluminum reacts with oxygen gas to produce aluminum oxide.

States of Matter

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Chem 110 Chapter 5 Test Review States of Matter: Gases, Liquids and Solids Changes in State Changes in state are considered physical changes. Other physical properties may also change during a change in state. 4 States of Matter are: Gases, Liquids, Solids Comparison of Physical Properties of Gases, Liquids, and Solids Property Gas Liquid Solid Volume and Shape Expands to fill the volume of its container and takes the shape of its container. Has a fixed volume at a given mass and temperature. Volume depends on its mass and temperature. It assumes the shape of its container. Has a fixed volume which is dependent on its mass and temperature. It has a definite shape. Density Compressibility Particle Motion Low High Virtually free High Very low

Chemical Equilibria checklist

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South Pasadena ( AP Chemistry [Keep for Reference] 16 ( Chemical Equilibria BLUFFER?S GUIDE ? 1. aA +bB + . . . rR +sS + . . . Kc = and for gases: Kp = 2. K > 1 products favored K < 1 reactants favored 3. Excluded: solids; pure liquids; water (in aqueous solutions) because their [ ]?s do not change. 4. Convert from Kc to Kp Kp = Kc(RT)(n where (n = moles of gaseous product ? moles of gaseous reactant. 5. Typical question: Given Kc and the starting concentrations of reactants, find concentrations of products at equilibrium. Example: Kc for acetic acid = 1.8 x 10-5. What is the equilibrium concentration of [H+] in a 0.100 M solution of the acid? 6. Equilibrium constant for a reverse reaction = the value of the forward reaction.

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