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Chemistry

Principles of Chemistry Chapter 7

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Chapter 7: Chemical Bonding Section 7.3: The Covalent Bond Wednesday, October 1, 2014 1:55 PM Covalent bonds - attractive force resulting from the sharing of electrons between pairs of atoms ? Chemical Bonds and Energy ? Driving force between all bond formation is lowering overall energy (NOTE: attractive interactions lower potential energy) ? Typically in interactions between nonmetals! ? -point of minimum energy in a system = formation of covalent bond Bond energy - energy released when isolated atoms form a covalent bond Bond length - distance between the nuclei of bonded atoms ? Formation of a chemical bond always releases energy Bond strength is determined by the amount of energy released in the formation of that bond (more released energy means stronger bond) ?

Principles of Chemistry Chapter 4

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Chapter 4: Stoichiometry Section 4.2: Fundamentals of Stoichiometry Monday, September 15, 2014 2:32 PM Stoichiometry - study of relationships between quantities of reactants and products in chem reactions ? Obtaining Ratios from Balanced Equations ? -from the coefficients in the equation, all atoms are in ratios with one another Equation: CH4 + 2O2 = CO2 + 2H2O Ex: 1 mol CH4 : 2 mol O2 AND 1 mol CH4 : 1 mol CO2 **these are called "mole ratios" -frequently written as fractions -"molar mass ratios" relate molecular mass and molar mass ? ? This is a typical approach to solving reaction stoichiometry! ? Keep in mind the units for your final answer (in this case, grams of water) -also, use unit cancellation ? ?

Principles of Chemistry Chapter 2

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Chapter 2: Atoms and Molecules Section 1: Insight into Polymers Wednesday, August 27, 2014 12:40 PM What is a polymer? -substance consisting of many large particles (called momoners) -monomers are small molecules made of many atoms ? note: the composition of the monomers determines the properties of the polymer ? All polymers have a polymer backbone, which is a long string of atoms keeping the molecule together. In organic chemistry, the backbone is made of carbon molecules! ? ? ? THE DIFFERENT COMBOS OF ATOMS MAKE DIFFERENT POLYMERS! ? ? ? ? Coulomb's Law describes interaction of charged particles. ? (remember the E is the permittivity constant) ? ? ? ? ?

Reactivity of Nuclear Muons

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preAP Chem 2013-2014 1 Name ________________________________ Note: It is very important that you note that some elements do not occur as single atoms when by themselves. If they are not combined with another element, they will bond with themselves, forming a _________________ molecule. In any chemical reaction, when you see these elements alone, they must be shown with a diatomic formula. Diatomic elements: H2, N2, O2, F2, Cl2, Br2, I2 I. Describing Chemical Change A. Writing Equations ? words can be used to describe _____________________________, but that can become long and ______________________. ? chemists use ___________________________ to describe reactions. In chemical equations,

Atomic Structure Notes

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Pre-AP Chemistry 1 Chapter ________ Name _____________________________ Period ______ I. Historical Development (3-1) x particle theory of matter first proposed by ________________________ in 400 BC ? named the basic particle the ?_______________?, which means ____________________ in Greek x by 1700?s most scientists accepted definition of an _____________ as a substance that cannot be broken down by ordinary ________________ means x also accepted that _______________ combine to form ________________ x _______________________: the transformation of a substance or substances into 1 or more

Organic Chapter 11 ppt

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Chapter 11 Reactions of Alcohols Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 11 * Types of Alcohol Reactions Dehydration to alkene Oxidation to aldehyde, ketone, acids Substitution to form alkyl halide Reduction to alkane Esterification Tosylation Williamson synthesis of ether => Chapter 11 Chapter 11 * Summary Table => Chapter 11 Chapter 11 * Oxidation States Easy for inorganic salts CrO42- reduced to Cr2O3 KMnO4 reduced to MnO2 Oxidation: loss of H2, gain of O, O2, or X2 Reduction: gain of H2 or H-, loss of O, O2, or X2 Neither: gain or loss of H+, H2O, HX => Chapter 11 Chapter 11 * 1?, 2?, 3? Carbons => Chapter 11 Chapter 11 * Sample Problems (1)

Organic Chapter 10 ppt

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Chapter 10 Structure and Synthesis of Alcohols Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 10 * Structure of Alcohols Hydroxyl (-OH) functional group Oxygen is sp3 hybridized. Versatile synthetic intermediates Chapter 10 Chapter 10 * Classification Determined by carbinol carbon atom: Primary: carbon with ?OH is bonded to one other carbon. Secondary: carbon with ?OH is bonded to two other carbons. Tertiary: carbon with ?OH is bonded to three other carbons. Aromatic (phenol): -OH is bonded to a benzene ring. Chapter 10 Chapter 10 * Classify these: Chapter 10 Chapter 10 * IUPAC Nomenclature Find the longest carbon chain containing the carbon with the -OH group.

Organic Chapter 9 ppt

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Chapter 9 Alkynes Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 9 * Introduction Alkynes (a.k.a. acetylenes) contain a triple bond. General formula is CnH2n-2. Two elements of unsaturation for each triple bond. Some reactions are like alkenes: addition and oxidation. Some reactions are specific to alkynes. Chapter 9 Alkynes in Nature Chapter 9 * Nomenclature: IUPAC Find the longest chain containing the triple bond. Change -ane ending to -yne. Number the chain, starting at the end closest to the triple bond. Give branches or other substituents a number to locate their position. => Chapter 9 Chapter 9 * Name these: propyne 5-bromo-2-pentyne

Organic Chapter 7 ppt

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Chapter 7 Structure and Synthesis of Alkenes Jo Blackburn Richland College, Dallas, TX Dallas County Community College District ? 2006, Prentice Hall Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 7 * Introduction Hydrocarbon with carbon-carbon double bonds Sometimes called olefins Term derived from olefiant gas meaning ?oil-forming gas? Originates with early experiments and the oily appearance of alkene derivatives Chapter 7 Chapter 7 * Characteristics Among most important industrial compounds and found in many plants and animals Ethylene ? a.k.a. ethene largest volume industrial organic compound used to make polyethylene and others Pinene ? major component of turpentine ? paint solvent distilled from extracts of evergreen trees Chapter 7 Chapter 7 *

Organic Chapter 6 ppt

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Chapter 6 Alkyl Halides: Nucleophilic Substitution and Elimination Organic Chemistry, 6h Edition L. G. Wade, Jr. Chapter 6 * Classes of Halides Alkyl: Halogen, X, is directly bonded to sp3 carbon. Most reactions result from breaking of this bond. C ? X bond is polar (EN difference) C is slightly positive ? electrophilic (can be attacked by nucleophile) X can leave with electrons ? elimination X can be replaced with another functional group ? substitution Chapter 6 Chapter 6 * Classes of Halides Examples: CHCl3 ? chloroform (solvent) CHClF2 ? freon-22 (refrigerant) CCl3 ? CH3 ? 1,1,1-trichloroethane (cleaning fluid) CF3 ? CHClBr ? halothane (nonflammable anesthetic) Chapter 6 Chapter 6 * Classes of Halides Vinyl: X is bonded to sp2 carbon of alkene. Examples:

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