Chemistry

1 Chapter 14 - Acids and Bases 14.1 The Nature of Acids and Bases A. Arrhenius Model 1. Acids produce hydrogen ions in aqueous solutions 2. Bases produce hydroxide ions in aqueous solutions B. Bronsted-Lowry Model 1. Acids are proton donors 2. Bases are proton acceptors 3. H3O+ is called the hydronium ion C. Conjugate Acid-Base Pairs 1. A conjugate base is what remains after an acid has donated a proton a. Cl- is the conjugate base of HCl 2. A conjugate acid is what is formed when a base accepts a proton base acid acid base 3. HCl is a stronger base than H3O+ (H+) so the equilibrium lies far to the right D. Acid Dissociation Constant 1. ][ ]][[ HCl ClHKa -+ = a. water is not included because, in dilute solution, the concentration of

1 Chapter 12 - Chemical Kinetics 12.1 Reaction Rates A. Chemical kinetics 1. Study of the speed with which reactants are converted to products B. Reaction Rate 1. The change in concentration of a reactant or product per unit of time [ ] t A tt ttimeatAofionconcentratttimeatAofionconcentratRate D D=- -= 12 12 a. Rates decrease with time b. It is customary to express reaction rates as positive values c. Instantaneous rate can be determined by finding the slope of a line tangent to a point representing a particular time C. Decomposition of NO2 2NO2(g) ? 2NO(g) + O2(g) Rate of consumption of NO2 = rate of production of NO = 2(rate of production of O2) [ ]t NO D D- 2 = [ ] t NO D D = [ ] ? ?

1 Chapter 10 - Liquids and Solids 10.1 Intermolecular Forces A. Dipole-Dipole Forces 1. Attraction between molecules with dipole moments a. Maximizes (+) ----- ( - ) interactions b. Minimizes (+) ----- ( + ) and (-) ----- ( - ) interactions 2. About 1% of strength of ionic bonds a. Unimportant in gas phase due to distance between molecules B. Hydrogen Bonding 1. Special dipole-dipole attraction a. Hydrogen covalently bonded to highly electronegative elements (N, O, F) has a higher than normal d+ charge 2. Bond strength is higher than other dipole-dipole attractions 3. Important in the bonding of molecules such as water and DNA C. London Dispersion Forces 1. Instantaneous dipoles a. Random movement of electrons can create a momentary

AP Chemistry A. Allan Chapter 8 Notes - Bonding: General Concepts 8.1 Types of Chemical Bonds A. Ionic Bonding 1. Electrons are transferred 2. Metals react with nonmetals 3. Ions paired have lower energy (greater stability) than separated ions B. Coulomb's Law 1. ? ? ? ? ? ? ? ? ?= - r QQ E nmJx 21191031.2 a. E = energy in joules b. Q1 and Q2 are numerical ion charges c. r = distance between ion center in nanometers d. negative sign indicates an attractive force C. Bond Length (covalent) 1. Distance at which the system energy is at a minimum 2. Forces at work a. Attractive forces (proton - electron) b. Repulsive forces (electron - electron, proton - proton) 3. Energy is given off (bond energy) when two atoms achieve greater stability together than apart

AP Chemistry A. Allan Chapter Six Notes - Thermochemistry 6.1 The Nature of Energy A. Definition 1. Energy is the capacity to do work (or to produce heat*) a. Work is a force acting over a distance (moving an object) b. *Heat is actually a form of energy. (1) chemicals may store potential energy in their bonds that can be released as heat energy B. Law of Conservation of Energy 1. Energy can be converted from one form to another, but cannot be created or destroyed a. Potential energy (1) energy due to position or composition b. Kinetic energy (1) energy due to the motion of an object (2) vmKE 22 1= C. Heat and Temperature 1. Temperature reflects random motion of particles in a substance 2. Temperature indicates the direction in which heat energy will flow